113. Mechanisms of aqueous bromate reduction activity enhancement with well-defined bimetallic palladium-based catalysts, J. P. Troutman, J. Restivo, H. Ha, Z. Bajalan, C. E. Brady, J. M. B. Costa, C. Vigil-Hernandez, J. R. M. Barbosa, C. A. Orge, M. F. R. Pereira, S. M. Humphrey, G. Henkelman, C. J. Werth, O. S. G. P. Soares, Applied Catalysis A: General, 2024, Volume 676, 119654. DOI:10.1016/j.apcata.2024.119654

112. Tuning the Selectivity of Nitrate Reduction via Fine Composition Control of RuPdNP Catalysts, J. P. Troutman, J. S. P. Mantha, H. Li, G. Henkelman, S. M. Humphrey, C. J. Werth, Small, 2024, 2308593. DOI:10.1002/smll.20222308593

111. Pd–Au–Cu Ternary Alloy Nanoparticles: Highly Tunable and Economical Nitrite Reduction Catalysts, P. Kunal, C. Yan, H. Guo, H. Li, C. E. Brady, M. Duncan, X. Zhan, C. J. Werth, G. Henkelman, S. M. Humphrey, ACS Catalysis, 2023, 13, 11945-11953. DOI: 10.1021/acscatal.3c01676

110. Low-valent Metals in Metal-organic Frameworks Via Post-synthetic Modification, J. L. Obeso, M. T. Huxley, J. A. de Los Reyes, S. M. Humphrey, I. A. Ibarra, R. A. Peralta, Angew. Chem. Int. Ed. 2023, e202309025. DOI: 10.1002/anie.202309025

109. We Need to Talk about New Materials Characterization, T. W. Hayton, S. M. Humphrey, B. M. Cossairt, R. L. Brutchey, Inorganic Chemistry, 2023, 62(33), 13165-13167. DOI: 10.1021/acs.inorgchem.3c02524

108. Selective adsorption of volatile organic compounds in metal-organic frameworks (MOFs), B. Siu, A. R. Chowdhury, Z. Yan, S. M. Humphrey, T. Hutter, Coordination Chemistry Reviews, , 2023, 485, 215119. DOI: 10.1016/j.ccr.2023.215119

107. Mn-CUK-1: A Flexible MOF for SO2, H2O, and H2S Capture, S. G. Dunning, N. K. Gupta, J. E. Reynolds III, M. Sagastuy-Breña, J. G. Flores, E. Martínez-Ahumada, E. Sánchez-González, V. M. Lynch, A. Gutiérrez-Alejandre, J. Aguilar-Pliego, K. Kim, I. A. Ibarra, S. M. Humphrey, Inorganic Chemistry, 2022, 61(38), 15037-15044. DOI: 10.1021/acs.inorgchem.2c02012

106. Sequential Post-Synthetic Modifications to a Phosphine Selenide Metal-Organic Framework: Removal of Se Protecting Group and Subsequent Coordination of Au(I) and Ag(I) to P(III) Sites, S. L. White, V. Lynch, S. G. Dunning, S. M. Humphrey, In Progress, 2021.

105. Investigating H2 Sorption in Isostructural Metal-Organic Frameworks M-CUK-1 (M = Co, Mg) Through Experimental and Theoretical Studies, S. Suepaul, K. A. Forrest, P. A. Georgiev, P. M. Forster, W. Lohstroh, V. Grzimek, S. G. Dunning, J. E. Reynolds III, S. M. Humphrey, J. Eckert, B. Space, T. Pham. DOI: 10.1021/acsami.1c20312

104. Low-Valent Metal Ions as MOF Pillars: A New Route Toward Stable and Multifunctional MOFs, R. E. Sikma, N. Katyal, S. Lee, J. W. Fryer, C. G. Romero, S. K. Emslie, E. Taylor, V. M. Lynch, J.-S. Chang, G. Henkelman, S. M. Humphrey
J. Am. Chem. Soc., 2021, 143, 13710-13720. DOI: 10.1021/jacs.1c05564

103. Magnetism and Luminescence of a MOF with Linear Mn3 Nodes Derived from an Emissive Terthiophene-Based Imidazole Linker, W. Wang, J. He, H. Guo, S. G. Dunning, S. M. Humphrey, R. A. Jones, Molecules, 2021, 26(14), 4286. – Alan H. Cowley Memorial Edition. DOI: 10.3390/molecules26144286

102. Methods and Diversity in the Synthesis of Metal-Organic Frameworks, S. L. White, M. W. Heinz, S. M. Humphrey, Book Chapter in Comprehensive Coordination Chemistry III, Elsevier, 2021. DOI: 10.1016/B978-0-08-102688-5.00086-6

101. Organometallic Chemistry at Various Length Scales: More Than Just Metal-Carbon Bonds Bring Chemists Together, J. Mindiola, M. Delferro, S. M. Humphrey, Organometallics, 2020, 39, 881-882. DOI: 10.1021/acs.organomet.0c00198

100. PdAg Alloy Nanocatalysts: Toward Economically Viable Nitrite Reduction in Drinking Water, J. P. Troutman, H. Li, A. M. Haddix, B. A. Kienzle, G. Henkelman, S. M. Humphrey, C. J. Werth, ACS Catal, 2020, 10, 7979–7989. DOI: 10.1021/acscatal.0c01538

99. CuxIr(1-x) Nanoalloy Catalyts Achieve Near 100% Selectivity for Aqueous Nitrite Reduction to NH3 Selectivity, H. Li, C. Yan, H. Guo, K. Shin, S. M. Humphrey, C. J. Werth, G. Henkelman, ACS Catal., 2020, 10, 7915–7921. DOI: 10.1021/acscatal.0c01604

98. Testing the Predictive Power of Theory for PdxIr(100‒x) Alloy Nanoparticles for the Oxygen Reduction Reaction, H. Guo, J. Trindell, H. Li, D. Fernandez, S. M. Humphrey, G. Henkelman, R. Crooks, J. Mater. Chem. A, 2020, 8421-8429. DOI: 10.1039/C9TA13711D

97. Hydro­thermal synthesis and crystal structure of poly[bis­(μ3-3,4-di­amino­benzoato)manganese], a layered coordination polymer, M. K. Khosa, P. T. Wood, S. M. Humphrey, W. T. A. Harrison, Acta Cryst., 2020, E76, 909-913. DOI: 10.1107/S2056989020006805

96. Reversible Solid-State Isomerism by Azobenzene-Loaded Large-Pore Isoreticular Mg-CUK-1, J. He, K. Aggarwal, N. Katyal, S. He, E. Chiang, S. G. Dunning, J. E. Reynolds III, A. Steiner, G. Henkelman, E. Que, S. M. Humphrey, J. Am. Chem. Soc., 2020, 142, 6467-6471. DOI: 10.1021/jacs.9b13793

95. In situ formation of a triselenane NSeN-pincer MOF and single-crystal-to-single-crystal oxidation, S. He, L. L. Allemond, S. G. Dunning, J. E. Reynolds III, V. M. Lynch, S. M. Humphrey, Chem. Commun., 2020, 56, 1286-1289. DOI: 10.1039/C9CC07851G

94. Hydrogen Evolution by Ni2P Catalysts Derived from Phosphine MOF, O. Mabayoje, S. G. Dunning, B. Wygant, R. Ciufo, K. Kawashima, S. M. Humphrey, C. B. Mullins, ACS Appl. Energy Mater., 2020, 3, 176-183. DOI: 10.1021/acsaem.9b02109

93. Stabilizer-Free CuIr Alloy Nanoparticle Catalysts, H. Guo, H. Li, D. Fernandez, S. Willis, K. Jarvis, G. Henkelman, S. M. Humphrey, Chem. Mater., 2019, 31, 10225-10235. DOI: 10.1021/acs.chemmater.9b04138

92. Rational Design of Rhodium-​Iridium Alloy Nanoparticles as Highly Active Catalysts for Acidic Oxygen Evolution, H. Guo, Z. Fang, H. Li, D. Fernandez, G. Henkelman, S. M. Humphrey, G. Yu, ACS Nano, 2019, 13, 13225-13234. DOI: 10.1021/acsnano.9b06244

91. Dipyrrolylnaphthyridine-based Schiff-base cryptands and their selective gas adsorption properties, F. Wang, R. E. Sikma, Z. Duan, C. Lei, Z. Zhang, S. M. Humphrey, J. L. Sessler
J. Porphyr. Phthalocya., 2019, 24, 424-431.

90. Accumulation-Driven Unified Spatiotemporal Synthesis and Structuring of Immiscible Metallic Nanoalloys, B. B. Rajeeva, P. Kunal, P. S. Kollipara, P. V. Acharya, M. Joe, M. S. Ide, K. Jarvis, Y. Liu, V. Bahadur, S. M. Humphrey, Y. Zheng
Matter, 2019, 1, 1606-1617. DOI: 10.1016/j.matt.2019.10.017

89. Direct, One-Pot Syntheses of MOFs Decorated with Low-Valent Metal-Phosphine Complexes, S. G. Dunning, J. E. Reynolds III, K. M. Walsh, D. J. Kristek, V. M. Lynch, P. Kunal, S. M. Humphrey
Organometallics, 2019, 38, 3406-3411. DOI: 10.1021/acs.organomet.9b00319

88. Porous Metal–Organic Framework CUK-1 for Adsorption Heat Allocation toward Green Applications of Natural Refrigerant Water, J. S. Lee, J. W. Yoon, P. G. M. Mileo, K. H. Cho, J. Park, H. Kim, M. F. de Lange, F. Kapteijn, G. Maurin, S. M. Humphrey, J.-S. Chang, ACS App. Mater. Interfaces, 2019, 11, 25778-25789. DOI: 10.1021/acsami.9b02605

87. Phosphonium zwitterions for lighter and chemically-robust MOFs: Highly reversible H2S capture and solvent-triggered release, J. E. Reynolds III, A. M. Bohnsack, D. J. Kristek, A. Gutiérrez-Alejandre, S. G. Dunning, N. W. Waggoner, R. E. Sikma, I. A. Ibarra, S. M. Humphrey, J. Mater. Chem. A, 2019, 7, 16842-16849. DOI: 10.1039/C9TA05444H

86. Shape-persistent pyrrole-based covalent organic cages: Synthesis, structure and selective gas adsorption properties, F. Wan, R. E. Sikma, Z. Duan, T. Sarma, C. Lei, Z. Zhang, S. M. Humphrey, J. L. Sessler, Chem. Commun., 2019, 55, 6185-6188. DOI: 10.1039/C9CC02490E

85. Humidity-induced CO2 capture enhancement in Mg-CUK-1
M. Sagastuy-Breña, P. G. M. Mileo, E. Sánchez-González, J. E. Reynolds, III, T. Jurado-Vázquez, J. Balmaseda, E. González-Zamora, S. Devautour-Vinot, S. M. Humphrey, G. Maurin, I. A. Ibarra, Dalton Trans., 2018, 47, 15827-15834. DOI:

84. Structural Characterization of Heterogeneous Rh-Au Nanoparticles from a Microwave-Assisted Synthesis, Z. Duan, J. Timoschenko, P. Kunal, S. House, H. Wan, K. Jarvis, C. Bonifacio, J. C. Yang, R. M. Crooks, A. I. Frenkel, S. M. Humphrey, G. Henkelman, Nanoscale, 2018, 10, 22520-22532. DOI: 10.1039/C8NR04866E

83. Highly Selective Room Temperature Acetylene Sorption by an Unusual Triacetylenic Phosphine MOF, J. E. Reynolds III, K. M. Walsh, B. Li, P. Kunal, B. Chen, S. M. Humphrey, Chem. Commun., 2018, 54, 9937-9940. DOI: 10.1039/C8CC05402A

82. An Organoarsine MOF with cis-Diarsine Pockets for the Installation of Uniquely Confined Metal Complexes, R. E. Sikma, P. Kunal, S. G. Dunning, J. E. Reynolds III, J.-S. Lee, J.-S. Chang, S. M. Humphrey, J. Am. Chem. Soc., 2018, 140, 9806-9809. DOI: 10.1021/jacs.8b05644

81. Microwave-Assisted Synthesis of Classically Immiscible Ag–Ir Alloy Nanoparticle Catalysts, H. Guo, H. Li, K. Jarvis, H. Wan, P. Kunal, S. G. Dunning, Y. Liu, G. Henkelman, S. M. Humphrey
ACS Catal., 2018, 8, 11386-11397.

80. Highly reversible sorption of H2S and CO2 by an environmentally-friendly Mg-based MOF, E. Sánchez-González, P. G. M. Mileo, M. Sagastuy-Breña, J. R. Álvarez, J. E. Reynolds III, A. Villarreal, A. Gutiérrez-Alejandre, J. Ramírez, J. Balmaseda, E. González-Zamora, G. Maurin, S. M. Humphrey, I. A. Ibarra
J. Mater. Chem. A, 2018, 6, 16900-16909. DOI: 10.1039/C8TA05400B

79. Optothermophoretic Manipulation of Colloidal Particles in Nonionic Liquids, X. Peng, L. Lin, E. H. Hill, P. Kunal, S. M. Humphrey, and Y. Zheng, J. Phys. Chem. C, 2018, J Phys Chem C Nanomater Interfaces. DOI:10.1021/acs.jpcc.8b03828

78. A MOF with Cooperative Phosphines that Permits Post‐Synthetic Installation of Open Metal Sites, S. G. Dunning, G. Nandra, A. D. Conn, W. Chai, R. E. Sikma, J.-S. Lee, P. Kunal, J. E. Reynolds III, J.-S. Chang, A. Steiner, G. Henkelman, S. M. Humphrey
Angew. Chem. Int. Ed., 2018, 57, 9295-9299. DOI: 10.1002/anie.201802402

77. 1-D and 2-D Phosphine Coordination Materials based on a Palladium(II) PCP Pincer Metalloligand, J. He, A. M. Bohnsack, N. W. Waggoner, S. G. Dunning, V. M. Lynch, W. C. Kaska, S. M. Humphrey, Polyhedron, 2018, 143, 149-156. DOI: 10.1016/j.poly.2017.09.025

76. A Survey of Metal-Organic Frameworks Based on Phosphorus- and Sulfur-Containing Building Blocks, J. E. Reynolds III, S. G. Dunning, C. M. McCulley, S. M. Humphrey, Book chapter in Elaboration and Applications of Metal-Organic Frameworks, World Scientific, 2018. DOI: 10.1142/9789813226739_0002

75. Oxygen Reduction Reaction on Classically Immiscible Bimetallics: A Case Study of RhAu, H. Li, L. Luo, P. Kunal, C. S. Bonifacio, Z. Duan, J. Yang, S. M. Humphrey, R. M. Crooks, G. Henkelman
J. Phys. Chem. C, 2018, 122, 2712-2716. DOI: 10.1021/acs.jpcc.7b10974

74. Highly Selective Adsorption of p-Xylene over other C8 Aromatic Hydrocarbons by Co-CUK-1: A Combined Experimental and Theoretical Assessment, J. W. Yoon, J. S. Lee, G. W. Piburn, K.-H. Cho, K. Jeon, H.-K. Lim, H. Kim, C.-H. Jun, S. M. Humphrey, R. Krishna, J. S. Chang, Dalton Trans., 2017, 46, 16096-16101. DOI: 10.1039/C7DT03304D

73. Synthesis and Characterization of a Binuclear Copper(II) Naphthoisoamethyrin Complex Displaying Weak Antiferromagnetic Coupling, J. T. Brewster II, G. Anguera, M. D. Moore, B. S. Dolinar, H. Zafar, G. D. Thiabaud, V. M. Lynch, S. M. Humphrey, J. L. Sessler, Inorg. Chem., 2017, 56, 12665-12669. DOI: 10.1021/acs.inorgchem.7b01669

72. Rapid Synthesis of RhPd Alloy Nanocatalysts
G. W. Piburn, H. Li, P. Kunal, G. Henkelman, S. M. Humphrey
ChemCatChem, 2017, 10, 329-333. DOI: 10.1002/cctc.201701133

71. Magnetic Properties of the Distorted Kagomé Lattice Mn3(1,2,4-(O2C)3C6H3)2, R. A. Mole, S. Greene, P. F. Henry, S. M. Humphrey, K. C. Rule, T. Unruh, G. F. Weldon, D. Yu, J. A. Stride, P. T. Wood
Inorg. Chem., 2017, 56, 7851-7860. DOI: 10.1021/acs.inorgchem.7b00597

70. Continuous Flow Synthesis of Rh and RhAg Alloy Nanoparticle Catalysts Enables Scalable Production and Improved Morphological Control, P. Kunal, E. J. Roberts, C. T. Riche, K. Jarvis, N. Malmstadt, R. J. Brutchey, S. M. Humphrey
Chem. Mater., 2017, 29, 4341-4350. DOI: 10.1021/acs.chemmater.7b00694

69. PdAu Alloy Nanoparticle Catalysts: Effective Candidates for Nitrite Reduction in Water, S. Seraj, P. Kunal, H. Li, G. Henkelman, S. M. Humphrey, C. J. Werth, ACS Catalysis, 2017, 7, 3268-3276. DOI: 10.1021/acscatal.6b03647

68. A sensor for trace H2O detection in D2O, S. G. Dunning, A. J. Nunez, M. D. Moore, A. Steiner, V. M. Lynch, J. L. Sessler, B. J. Holliday, S. M. Humphrey, Chem, 2017, 2, 579-589. DOI: 10.1016/j.chempr.2017.02.010

67. Synthesis and charge storage properties of templated LaMnO3-SiO2 composite materials, G. W. Piburn, J. T. Mefford, N. Zinni, K. J. Stevenson, S. M. Humphrey, Dalton Trans., 2017, 46, 977-984. DOI: 10.1039/C6DT04665G

66. A PCP Pincer Ligand for Coordination Polymers with Versatile Chemical Reactivity: Selective Activation of CO2 Gas over CO Gas in the Solid State, J. He, N. W. Waggoner, S. G. Dunning, A. Steiner, V. M. Lynch, S. M. Humphrey, Angew. Chem. Int. Ed. 2016, 55, 12351-12355. DOI: 10.1002/anie.201604730

65. Microwave-​Assisted Synthesis of PdxAu100-​x Alloy Nanoparticles: A Combined Experimental and Theoretical Assessment of Synthetic and Compositional Effects upon Catalytic Reactivity, P. Kunal, H. Li, B. L. Dewing, L. Zhang, K. Jarvis, G. Henkelman, S. M. Humphrey, ACS Catalysis. 2016, 6, 4882-4893. DOI: 10.1021/acscatal.6b01014

64. Ship in a breakable bottle: fluoride-induced release of an organic molecule from a Pr(III)-linked molecular cage, J. Lee, N. W. Waggonner, L. Polanco, G. R. You, V. M. Lynch, S. K. Kim, S. M. Humphrey, J. L. Sessler, Chem. Commun. 2016, 52, 8514-8517. DOI: 10.1039/C6CC03471C

63. An unusual coordination polymer containing Cu+ ions and featuring possible Cu⋯Cu ‘cuprophilic’ interactions: poly[di-μ-chlorido-(μ4-3,5-diaminobenzoato-κ4O:O’:N:N’)tricopper(I)(3 Cu-Cu)] , M. K. Khosa, P. T. Wood, S. M. Humphrey, W. T. A. Harrison, Acta Cryst. 2016, C72, 63-67. DOI: 10.1107/S205322961502330X

62. Inelastic Neutron Scattering and Theoretical Studies of H2 Sorption in a Dy(III)-Based Phosphine Coordination Material, K. A. Forrest, T. Pham, P. A. Georgiev, J. P. Embs, N. W. Waggoner, A. Hogan, S. M. Humphrey, J. Eckert, B. Space, Chem. Mater. 2015, 27, 7619–7626. DOI: 10.1021/acs.chemmater.5b02747

61. Separation of p-divinylbenzene by selective room-temperature adsorption inside Mg-CUK-1 prepared by aqueous microwave synthesis, B. Saccoccia, A. M. Bohnsack, N. W. Waggonner, K-H. Cho, J-S. Lee, D-Y. Hong, J-S. Chang, S. M. Humphrey, Angew. Chem. Int. Ed. 2015, 54, 5394-5398. DOI: 10.1002/anie.201411862

60. Metal-Organic Frameworks as Chemical Sensors, N. W. Waggoner, A. M. Bohnsack, S. M. Humphrey, book chapter in Functional Supramolecular Materials, Royal Society of Chemistry, 2015. RSC Smart Materials, 2015, 15, 192-245.

59. Magnetism of linear [Ln3]9+ oxo-bridged clusters (Ln = Pr, Nd) supported inside a [R3PR’]+ phosphonium coordination material, N. W. Waggoner, B. Saccoccia, I. A. Ibarra, V. M. Lynch, P. T. Wood, S. M. Humphrey, Inorg. Chem. 2014, 53, 12674-12676. DOI: 10.1021/ic5023642

58. Microwave synthesis of classically immiscible rhodium-silver and rhodium-gold alloy nanoparticles: Highly active hydrogenation catalysts, S. Garcia, L. Zhang, G. W. Piburn, G. Henkelman, S. M. Humphrey, ACS Nano 2014, 8 11512-11521. DOI: 10.1021/nn504746u

57. Microwave-assisted Synthesis of Metallic Nanoparticles, S. Garcia, G. W. Piburn, S. M. Humphrey, book chapter in Microwave Engineering of Materials and Nanomaterials, Pan Stanford Publishing, 2014.

56. Effect of microwave heating on the synthesis of rhodium nanoparticles in ionic liquids, S. Garcia, J. J. Buckley, R. L. Brutchey, S. M. Humphrey, Inorg. Chim. Acta 2014, 422, 65-69.

55. Li- and Na-reduction products of meso-Co3O4 form high-rate, stably cycling battery anode materials, K. C. Klavetter, S. Garcia, N. Dahal, J. L. Snider, J. P. de Souza, T. H. Cell, M. A. Cassara, A. Heller, S. M. Humphrey, C. B. Mullins, J. Mater. Chem. A 2014, 2, 14209. DOI: 10.1039/C4TA02684E

54. Bis(imino)acenaphthene (BIAN)-supported palladium(II) carbene complexes as effective C-C coupling catalysts and solvent effects in organic and aqueous media, K. A. Crawford, A. H. Cowley, S. M. Humphrey, Catal. Sci. Technol. 2014, 4, 1456. DOI: 10.1039/C4CY00192C

53. Tuning the Host-Guest Interactions in a Phosphine Coordination Polymer Through Different Types of Post-Synthetic Modification, A. J. Nuñez, Maxwell S. Chang, I. A. Ibarra, S. M. Humphrey, Inorg. Chem. 2014, 53, 282. DOI: 10.1021/ic4022239

52. Rational Design of Porous Coordination Polymers Based on Bis(phosphine)MCl2 Compelxes That Exhibit High-Temperature H2 Sorption and Chemical Reactivity, A. M. Bohnsack, I. A. Ibarra, V. I. Bakhmutov, V. M. Lynch, S. M. Humphrey, J. Am. Chem. Soc. 2013, 135, 16038-16041. DOI: 10.1021/ja408508m

51. Rhenium(I) Phenanthrolines Bearing Electron Withdrawing CF3 Substituents: Synthesis, Characterization and Biological Evaluation, C. Redshaw, S. Watkins, S. M. Humphrey, P. C. B. Page, S. Ashby, Y. Chao, C. J. Herbert, A. Müller RSC Advances 2012, 3, 23963-23966. DOI: 10.1039/C3RA43207F

50. Molecular Sensing and Discrimination by a Luminescent Terbium-Phosphine Oxide Coordination Material, I. A. Ibarra, T. W. Hesterberg, J. Chang, J. W. Yoon, B. J. Holliday, S. M. Humphrey, Chem. Commun. 2013, 49, 7156-7158. DOI: 10.1039/C3CC44575E

49. Microwave Synthesis of Au-Rh Core-Shell Nanparticles and Implications of the Shell Thickness in Hydrogenation Catalysis, S. García, N. Dahal, J. Zhou, H. Celio, A. Dolocan, S. M. Humphrey, Chem Commun. 2013, 49, 4241. DOI: 10.1039/C3CC40387D

48. New Structural Motifs in Lithium and Zinc Calix[4]arene Chemistry, C. Redshaw, O. Rowe, D. L. Hughes, A. Fuller, I. A. Ibarra, and S. M. Humphrey, Dalton Trans. 2013, 42, 1983. DOI: 10.1039/C2DT32986G

47. Beneficial Effects of Microwave-Assisted heating versus Conventional Heating in Noble Metal Nanoparticle Synthesis, N. Dahal, S. García, J. Zhou, S. M. Humphrey, ACS Nano. 2012. DOI: 10.1021/nn3038918

46. Organic Vapor Sorption in a High Surface Area Dysprosium(III)-Phosphine Oxide Coordination Material, I. A. Ibarra, J. W. Yoon, J.-S. Chang, S.-K. Lee, V. M. Lynch, S. M. Humphrey, Inorg. Chem. 2012. DOI: 10.1021/ic301415p

45. Gas Sorption and Luminescence properties of a Terbium(III)-Phosphine Oxide Coordination Material with Two-Dimensional Pore Topology, Ibarra, I. A., Hesterberg, T. W., Holliday, B. D., Lynch, V. M., Humphrey, S. M., Dalton Trans. 2012, 41, 3920. DOI: 10.1039/C2DT30138E

44. High Surface Area Mesoporous Co3O4 from a Direct Soft-Template Route, N. Dahal, I. A. Ibarra, S. M. Humphrey, J. Mater. Chem. 2012, 22, 12675. DOI: 10.1039/C2JM30460K

43. CO2 adsorption properties of a Ca(II)-based organophosphonium coordination material, I. A. Ibarra, K. E. Tan, V. M. Lynch, S. M. Humphrey, Dalton Trans. 2012, 41, 3920. DOI: 10.1039/C2DT12011A

42. A Coordination Polymer of (Ph3P)AuCl Prepared by Post-Synthetic Modification and its Application in 1-Hexene/n-Hexane Separation, A. J. Nuñez, L. N. Shear, N. Dahal, I. A. Ibarra, J. W. Yoon, J.-S. Chang, S. M. Humphrey, Chem. Commun. 2011, 47, 11855. DOI: 10.1039/C1CC14682C

41. High capacity CO2 adsorption in a Mg(II)-based phosphine oxide coordination material, A. M. Bohnsack, I. A. Ibarra, P. W. Hatfield, Y. K. Hwang, J. W. Yoon, J.-S. Chang, S. M. Humphrey, Chem. Commun. 2011, 47, 4899. DOI: 10.1039/C1CC14682C

Previous Publications

40. Sonagashira coupling catalyzed by gold nanoparticles: does homogeneous or heterogeneous catalysis dominate?, G. Kyriahou, S. K. Beaumont, S. M. Humphrey, C. Antonetti, R. M. Lambert, ChemCatChem, 2010, 2, 1444. DOI: 10.1002/cctc.201000154

39. Mixed Alkali Metal/Transition Metal Coordination Polymers with the Mellitic Acid Hexaanion: 2-Dimensional Hexagonal Magnetic Nets, S. M. Humphrey, R. A. Mole, R. I. Thompson, P. T. Wood, Inorg. Chem. 2010, 49, 3441. DOI: 10.1021/ic902527e

38. Pyridine-2,4-Dicarboxylate: A Versatile Building Block for the Preparation of Functional Coordination Polymers, S. M. Humphrey, G. F. Weldon, P. T. Wood, J. Nanosci. Nanotech. 2010, 10, 34. DOI: 10.1166/jnn.2010.1505

37. Evidence for Heterogeneous Sonogashira Coupling of Phenylacetylene and Iodobenzene Catalyzed by Well Defined Rhodium Nanoparticles, V. K. Kanuru, S. M. Humphrey, J. M. W. Kyffin, D. A. Jefferson, J. Burton, R. M. Lambert, Dalton Trans. 2009, 7602. DOI: 10.1039/B912833F

36. Metal-Organophosphine and Metal-Organophosphonium Frameworks with Layered Honeycomb-like Structures, S. M. Humphrey, P. K. Allan, S. E. Oungoulian, M. S. Ironside, E. R. Wise, Dalton Trans. 2009, 2298. DOI: 10.1039/B820038F

35. Hysteretic Sorption of Light Gases by a Porous Metal-Organic Framework Containing Tris(­p­-Carboxylated) Triphenylphosphine Oxide, S. M. Humphrey, S. E. Oungoulian, Y. K. Hwang, E. R. Wise, J. W. Yoong, J.-S. Chang, Chem. Commun. 2008, 2891. DOI: 10.1039/B802809E

34. A Tin(II)-Containing Ansa-Tris(allyl) ligand and its Potassium Complex, R. A. Layfield, F. García, J. Hannauer, S. M. Humphrey, Chem. Commun. 2007, 5081. DOI: 10.1039/B712285C

33. Bimetallic Metal-Organic Frameworks Containing the [M(2,x-pdc)2]2- (M = Cu, Pd, Pt; x = 4,5) Building Block: Synthesis, Structure and Magnetic Properties, S. M. Humphrey, T. J. P. Angliss, M. Aransay, D. Cave, L. A. Gerrard, G. F. Weldon, P. T. Wood, Zeit. Anorg. Allg. Chem. 2007, 633, 2342. DOI: 10.1002/zaac.200700235

32. Gas-Sorption Selectivity on a Porous Coordination Solid of Co(II), CUK-1, J. W. Yoon, S. H. Jhung, Y. K. Hwang, S. M. Humphrey, P. T. Wood, J.-S. Chang , Adv. Mater. 2007, 19, 1830. DOI: 10.1002/adma.200601983

31. The Synthesis, Structure and Reactivity of B(C65)3-Stabilised Amide (M-NH2) Complexes of the Group 4 Metals, A. J. Mountford, W. Clegg, S. J. Coles, R. W. Harrington, P. N. Horton, S. M. Humphrey, M. B. Hursthouse, J. A. Wright, S. J. Lancaster, Chem. Eur. J. 2007, 13, 4535. DOI: 10.1002/chem.200601751

30. Charge-Transfer Interaction of Poly(vinylpyrrolidone) with Platinum and Rhodium Nanoparticles, Y. Borodko, S. M. Humphrey, T. D. Tilley, H. Frei, G. A. Somorjai, J. Phys. Chem. C. 2007, 111, 6288. DOI: 10.1021/jp068742n

29. Rhodium Nanoparticles from Cluster Seeds: Control of Size and Shape by Precursor Addition Rate, S. M. Humphrey, M. E. Grass, S. E. Habas, K. Niesz, G. A. Somorjai, T. D. Tilley, Nano Lett. 2007, 7, 785. DOI: 10.1021/nl070035y

28. Porous Cobalt(II)-Organic Frameworks with Corrugated Walls: Robust Gas-Sorption Materials, S. M. Humphrey, J.-S. Chang, S. H. Jhung, J. W. Yoon, P. T. Wood, Angew. Chem., Int. Ed. 2007, 46, 272. DOI: 10.1002/anie.200601627

27. The Cationic Cluster Grignard [{MgCl(thf)2}33-C3H5)2]+, R. A. Layfield, T. H. Bullock, F. García, S. M. Humphrey, P. Schüler, Chem. Commun. 2006, 2039. DOI: 10.1039/B602059C

26. A New Co(II) Coordination Solid with Mixed Oxygen, Carboxylate, Pyridine and Thiolate Donors Exhibiting Canted Antiferromagnetism with Tc ≈ 68 K, S. M. Humphrey, A. Alberola, C. J. Gómez García, P. T. Wood, Chem. Commun. 2006, 1607. DOI: 10.1039/B600347H

25. Complexes of Tungsten (IV,VI) Derived from Linked Aryloxide Ligands, C. Redshaw, S. M. Humphrey, Polyhedron 2006, 25, 1946. DOI: 10.1016/j.poly.2005.12.008

24. Spin Transitions in a Dithiazolyl Radical: Preparation, Crystal Structures and Magnetic Properties of 3-Cyanobenzo-1,2,3-dithiazolyl, C7H3S2N2•, A. Alberola, R. J. Collis, S. M. Humphrey, R. J. Less, J. M. Rawson, Inorg. Chem. 2006, 45, 1903. DOI: 10.1021/ic051935p

23. Ligand Transfer Reactions of Mixed-Metal Lanthanide/Magnesium Allyl Complexes with b-Diketimines: Synthesis, Structures, and Ring-Opening polymerization Catalysis, L. F. Sánchez-Barba, D. L. Hughes, S. M. Humphrey, M. Bochmann, Organometallics, 2006, 25, 1012. DOI: 10.1021/om050892h

22. Titanium, Zinc and Alkaline-Earth Metal Complexes Supported by Bulky O,N,N,O-Multidentate Ligands: Synthesis, Characterisation and Activity in Cyclic Ester Polymerisation, Y. Sarazin, R. H. Howard, D. L. Hughes, S. M. Humphrey, M. Bochmann, Dalton Trans. 2006, 340. DOI: 10.1021/om050892h

21. EPR Studies on the Thiophenodithiazolyl radical, C4H2S3N•, A. Alberola, R. D. Farley, S. M. Humphrey, G. D. McManus, D. M. Murphy, J. M. Rawson, Dalton Trans. 2005, 3838. DOI: 10.1039/B508912C

20. Synthesis and Structure of [trans-{1,2-Bis(η2-O,N,N-phenylcarbamoyl)cyclopentadienyl bis(thf)} magnesium]·4thf, R. A. Layfield, S. M. Humphrey, Organometallics 2005, 24, 6063. DOI: 10.1021/om050680k

19. Synthesis and Structures of New Mixed-Metal Lanthanide/Magnesium Allyl Complexes, L. F. Sánchez-Barba, D. L. Hughes, S. M. Humphrey, M. Bochmann, Organometallics 2005, 24, 5329. DOI: 10.1021/om0505155

18. Isolated Magnetic Clusters of Co(II) and Ni(II) within 3-Dimensional Organic Frameworks of 6-Mercaptonicotinic Acid: Unique Structural Topologies Based on Selectivity for Hard and Soft Coordination Environments, S. M. Humphrey, R. A. Mole, M. McPartlin, E. J. L. McInnes, P. T. Wood, Inorg. Chem. 2005, 44, 5981. DOI: 10.1021/ic050768q

17. New Bis(allyl)(diketiminato) and Tris(allyl) Lanthanide Complexes and Their Reactivity in the Polymerization of Polar Monomers, L. F. Sánchez-Barba, D. L. Hughes, S. M. Humphrey, M. Bochmann, Organometallics 2005, 24, 3792. DOI: 10.1021/om050309x

16. Quadruple Deprotonation of 2-Aminophenylphosphane with a p-Block-Metal/Alkali-Metal Base, F. García, S. M. Humphrey, R. A. Kowenicki, E. J. L. McInnes, C. M. Pask, M. McPartlin, J. M. Rawson, M. L. Stead, A. D. Woods, D. S. Wright, Angew. Chem., Int. Ed. 2005, 44, 3456. DOI: 10.1002/anie.200500340

15. New Titanium and Zirconium Complexes with M-NH2 Bonds Formed by Facile Deprotonation with H3N·B(C6F5)3, A. J. Mountford, W. Clegg, R. W. Harrington, S. M. Humphrey. S. J. Lancaster, Chem. Commun. 2005, 2044. DOI: 10.1039/B500407A

14. Variable Solid State Aggregations in a Series of (Isocyanide)Gold(I) Halides with the Novel Trimethylamine-Isocyanoborane Adduct, S. M. Humphrey, H-G. Mack, C. Redshaw, M. R. J. Elsegood, K. J. H. Young, H. A. Mayer, W. C. Kaska, Dalton Trans. 2005, 439. DOI: 10.1039/B416392C

13. Synthesis, Ion Aggregation, Alkyl Bonding Modes, and Dynamics of 14-Electron Matallocenium Ion Pairs [(SBI)MCH2SiMe3+···X] (M = Zr, Hf): Inner-Sphere (X = MeB(C6F5)3) Structures versus Outer-Sphere (X = B(C6F5)4) Structures and the Implications for “Continuous” or “intermittent” Alkene Polymerization Mechanisms, F. Song, S. J. Lancaster, R. D. Cannon, M. Schormann, S. M. Humphrey, C. Zuccaccia, A. Macchioni, M. Bochmann, Organometallics 2005, 24, 1315. DOI: 10.1021/om049248d

12. Highly Selective Epoxidation of Styrene using a Transition Metal-Aluminium(III) Complex Containing the [MeAl(2-py)3] Anion (2-py = 2-pyridyl), C. Soria Alvarez, F. García, S. M. Humphrey, A. D. Hopkins, R. A. Kowenicki, M. McPartlin, R. A. Layfield, R. Raja, M. C. Rogers, A. D. Woods, D. S. Wright, Chem. Commun. 2005, 198. DOI: 10.1039/B413488E

11. Acid/Amide Bonding for Anthranilic Acid Derivatives: Crystal Structures [W(X)Cl3(HO2CC6H4NH-2)] (X = O, NPh), S. M. Humphrey, C. Redshaw, K. E. Holmes, M. R. J. Elsegood, Inorg. Chim. Acta 2005, 358, 222. DOI: 10.1039/B413488E

10. Synthesis and Structure of [{Sn2(η-PMes)3}K2·3THF}, Exhibiting Multifunctional Coordination of [Sn2(m-PMes)3]2- Anions to K+, F. García, A. D. Hopkins, S. M. Humphrey, M. McPartlin, C. M. Pask, A. D. Woods, D. S. Wright, Organometallics 2004, 23, 4821. DOI: 10.1021/om0495372

9. Multiple Areas of Magnetic Bistability in the Topological Ferrimagnet [Co3(NC5H3(CO2)2-2,5)23-OH)2(OH2)2], S. M. Humphrey, P. T. Wood, J. Am. Chem. Soc. 2004, 126, 13236. DOI: 10.1021/ja046351l

8. Synthesis and Structure of [{Sn2(η-PMes)3}K2·3THF}, Exhibiting Multifunctional Coordination of [Sn2(m-PMes)3]2- Anions to K+, F. García, A. D. Hopkins, S. M. Humphrey, M. McPartlin, C. M. Pask, A. D. Woods, D. S. Wright, Organometallics 2004, 23, 4821. DOI: 10.1021/om0495372

7. [{H3C)3NB(H)2NC}2Au][AuI2]: A Linear Chain Polymer of Gold(I) Iodide with an Unusual Isocyanoborane Ligand Showing Aurophilic Behaviour, W. C. Kaska, H. A. Mayer, M. R. J. Elsegood, P. N. Horton, M. B. Hursthouse, C. Redshaw, S. M. Humphrey, Acta Cryst. 2004, E60, m563. DOI: 10.1107/S1600536804008098

6. A Manganese(II) Allyl Complex: Synthesis, Structure and Magnetic Properties of [Li(thf)4][Mn{η3-(Me3Si)2C3H3}{η1-(Me3Si)2C3H3}2], R. A. Layfield, S. M. Humphrey, Angew. Chem., Int. Ed. 2004, 43, 3067. DOI: 10.1002/ange.200454008

5. Hydrothermal Synthesis and Magnetic Properties of Novel Mn(II) and Zn(II) Materials with Thiolato-Carboxylate Donor Ligand Frameworks, S. M. Humphrey, R. A. Mole, J. M. Rawson, P. T. Wood, Dalton Trans. 2004, 1670. DOI: 10.1039/B401887G

4. Selective Formation of the [PhP(H)-PPh] Anion in the Reaction of PhPHLi with MeAlCl2: Synthesis and Structure of the Unusual Tetramer [{PhP(H)-PPh}Li·thf]4, F. García, S. M. Humphrey, R. A. Kowenicki, M. McPartlin, D. S. Wright, Dalton Trans. 2004, 977. DOI: 10.1039/B402295E

3. Steric Control in the Oligomerization of Phosphazene Dimers; Towards New Phosphorus-Nitrogen Macrocycles, E. L. Doyle, F. García, S. M. Humphrey, R. A. Kowenicki, L. Riera, A. D. Woods, D. S. Wright, Dalton Trans. 2004, 807. DOI: 10.1039/B314790H

2. The First Example of a Si-Bridged Tris(pyridyl) Ligand; Synthesis and Structure of [MeSi(2-C5H4N)3LiX] (X = 0.2Br, 0.8Cl), F. García, A. D. Hopkins, S. M. Humphrey, M. McPartlin, M. C. Rogers, D. S. Wright, Dalton Trans. 2004, 361. DOI: 10.1039/B315503J

1. 2,2´-Disulfanyldibenzoic Acid, S. M. Humphrey, P. T. Wood, Acta Cryst. 2003, E59, o1364. DOI: 10.1107/S1600536803017306