Publications

2020 Publications

Organometallic Chemistry at Various Length Scales: More Than Just Metal-Carbon Bonds Bring Chemists Together
D.J. Mindiola, M. Delferro, S.M. Humphrey
Organometallics, 2020, 39, 881-882.

PdxAuyCu(100-x-y) Ternary Alloy Nanoparticles: Highly Tunable and Economical Reduction Catalysis
P. Kunal, H. Guo, C. Yan, H. Li, S.G. Dunning, M. Duncan, K. Jarvis, C.J. Werth, G. Henkelman, S.M. Humphrey
Submitted.

PdAg Alloy Nanocatalysts: Toward Economically Viable Nitrite Reduction in Drinking Water
J. P. Troutman, H. Li, A. M. Haddix, B. A. Kienzle, G. Henkelman, S. M. Humphrey, C. J. Werth
ACS Catal, 2020, Accepted, available online.

CuxIr(1-x) Nanoalloy Catalyts Achieve Near 100% Selectivity for Aqueous Nitrite Reduction to NH3 Selectivity
H. Li, C. Yan, H. Guo, K. Shin, S. M. Humphrey, C. J. Werth, G. Henkelman
ACS Catal., 2020, Accepted, available online.

Testing the Predictive Power of Theory for PdxIr(100‒x) Alloy Nanoparticles for the Oxygen Reduction Reaction
H. Guo, J. Trindell, H. Li, D. Fernandez, S. M. Humphrey, G. Henkelman, R. Crooks
J. Mater. Chem. A, 2020, 8421-8429.

Reversible Solid-State Isomerism by Azobenzene-Loaded Large-Pore Isoreticular Mg-CUK-1
J. He, K. Aggarwal, N. Katyal, S. He, E. Chiang, S. G. Dunning, J. E. Reynolds III, A. Steiner, G. Henkelman, E. Que, S. M. Humphrey
J. Am. Chem. Soc., 2020, 142, 6467-6471.

In situ formation of a triselenane NSeN-pincer MOF and single-crystal-to-single-crystal oxidation
S. He, L. L. Allemond, S. G. Dunning, J. E. Reynolds III, V. M. Lynch, S. M. Humphrey
Chem. Commun., 2020, 56, 1286-1289.

Hydrogen Evolution by Ni2P Catalysts Derived from Phosphine MOFs
O. Mabayoje, S. G. Dunning, B. Wygant, R. Ciufo, K. Kawashima, S. M. Humphrey, C. B. Mullins
ACS Appl. Energy Mater., 2020, 3, 176-183.

2019 Publications

Stabilizer-Free CuIr Alloy Nanoparticle Catalysts
H. Guo, H. Li, D. Fernandez, S. Willis, K. Jarvis, G. Henkelman, S. M. Humphrey
Chem. Mater., 2019, 31, 10225-10235.

Rational Design of Rhodium-​Iridium Alloy Nanoparticles as Highly Active Catalysts for Acidic Oxygen Evolution
H. Guo, Z. Fang, H. Li, D. Fernandez, G. Henkelman, S. M. Humphrey, G. Yu
ACS Nano, 2019, 13, 13225-13234.

Dipyrrolylnaphthyridine-based Schiff-base cryptands and their selective gas adsorption properties
F. Wang, R. E. Sikma, Z. Duan, C. Lei, Z. Zhang, S. M. Humphrey, J. L. Sessler
J. Porphyr. Phthalocya., 2019, 24, 424-431.

Accumulation-Driven Unified Spatiotemporal Synthesis and Structuring of Immiscible Metallic Nanoalloys
B. B. Rajeeva, P. Kunal, P. S. Kollipara, P. V. Acharya, M. Joe, M. S. Ide, K. Jarvis, Y. Liu, V. Bahadur, S. M. Humphrey, Y. Zheng
Matter, 2019, 1, 1606-1617.

Direct, One-Pot Syntheses of MOFs Decorated with Low-Valent Metal-Phosphine Complexes
S. G. Dunning, J. E. Reynolds III, K. M. Walsh, D. J. Kristek, V. M. Lynch, P. Kunal, S. M. Humphrey
Organometallics, 2019, 38, 3406-3411.

Porous Metal–Organic Framework CUK-1 for Adsorption Heat Allocation toward Green Applications of Natural Refrigerant Water
J. S. Lee, J. W. Yoon, P. G. M. Mileo, K. H. Cho, J. Park, H. Kim, M. F. de Lange, F. Kapteijn, G. Maurin, S. M. Humphrey, J.-S. Chang
ACS App. Mater. Interfaces, 2019, 11, 25778-25789.

Phosphonium zwitterions for lighter and chemically-robust MOFs: Highly reversible H2S capture and solvent-triggered release
J. E. Reynolds III, A. M. Bohnsack, D. J. Kristek, A. Gutiérrez-Alejandre, S. G. Dunning, N. W. Waggoner, R. E. Sikma, I. A. Ibarra, S. M. Humphrey
J. Mater. Chem. A, 2019, 7, 16842-16849.

Shape-persistent pyrrole-based covalent organic cages: Synthesis, structure and selective gas adsorption properties
F. Wan, R. E. Sikma, Z. Duan, T. Sarma, C. Lei, Z. Zhang, S. M. Humphrey, J. L. Sessler
Chem. Commun., 2019, 55, 6185-6188.

2018 Publications

Humidity-induced CO2 capture enhancement in Mg-CUK-1
M. Sagastuy-Breña, P. G. M. Mileo, E. Sánchez-González, J. E. Reynolds, III, T. Jurado-Vázquez, J. Balmaseda, E. González-Zamora, S. Devautour-Vinot, S. M. Humphrey, G. Maurin, I. A. Ibarra
Dalton Trans., 2018, 47, 15827-15834.

Structural Characterization of Heterogeneous Rh-Au Nanoparticles from a Microwave-Assisted Synthesis
Z. Duan, J. Timoschenko, P. Kunal, S. House, H. Wan, K. Jarvis, C. Bonifacio, J. C. Yang, R. M. Crooks, A. I. Frenkel, S. M. Humphrey, G. Henkelman
Nanoscale, 2018, 10, 22520-22532.

Highly Selective Room Temperature Acetylene Sorption by an Unusual Triacetylenic Phosphine MOF
J. E. Reynolds III, K. M. Walsh, B. Li, P. Kunal, B. Chen, S. M. Humphrey
Chem. Commun., 2018, 54, 9937-9940.

An Organoarsine MOF with cis-Diarsine Pockets for the Installation of Uniquely Confined Metal Complexes
R. E. Sikma, P. Kunal, S. G. Dunning, J. E. Reynolds III, J.-S. Lee, J.-S. Chang, S. M. Humphrey
J. Am. Chem. Soc., 2018, 140, 9806-9809.

Microwave-Assisted Synthesis of Classically Immiscible Ag–Ir Alloy Nanoparticle Catalysts
H. Guo, H. Li, K. Jarvis, H. Wan, P. Kunal, S. G. Dunning, Y. Liu, G. Henkelman, S. M. Humphrey
ACS Catal., 2018, 8, 11386-11397.

Highly reversible sorption of H2S and CO2 by an environmentally-friendly Mg-based MOF
E. Sánchez-González, P. G. M. Mileo, M. Sagastuy-Breña, J. R. Álvarez, J. E. Reynolds III, A. Villarreal, A. Gutiérrez-Alejandre, J. Ramírez, J. Balmaseda, E. González-Zamora, G. Maurin, S. M. Humphrey, I. A. Ibarra
J. Mater. Chem. A, 2018, 6, 16900-16909.

Optothermophoretic Manipulation of Colloidal Particles in Nonionic Liquids
X. Peng, L. Lin, E. H. Hill, P. Kunal, S. M. Humphrey, and Y. Zheng
J. Phys. Chem. C, 2018, Accepted. DOI:10.1021/acs.jpcc.8b03828

A MOF with Cooperative Phosphines that Permits Post‐Synthetic Installation of Open Metal Sites
S. G. Dunning, G. Nandra, A. D. Conn, W. Chai, R. E. Sikma, J.-S. Lee, P. Kunal, J. E. Reynolds III, J.-S. Chang, A. Steiner, G. Henkelman, S. M. Humphrey
Angew. Chem. Int. Ed., 2018, 57, 9295-9299.

1-D and 2-D Phosphine Coordination Materials based on a Palladium(II) PCP Pincer Metalloligand
J. He, A. M. Bohnsack, N. W. Waggoner, S. G. Dunning, V. M. Lynch, W. C. Kaska, S. M. Humphrey
Polyhedron, 2018, 143, 149-156.

A Survey of Metal-Organic Frameworks Based on Phosphorus- and Sulfur-Containing Building Blocks
J. E. Reynolds III, S. G. Dunning, C. M. McCulley, S. M. Humphrey,
Book chapter in Elaboration and Applications of Metal-Organic Frameworks, World Scientific, 2018.

Oxygen Reduction Reaction on Classically Immiscible Bimetallics: A Case Study of RhAu
H. Li, L. Luo, P. Kunal, C. S. Bonifacio, Z. Duan, J. Yang, S. M. Humphrey, R. M. Crooks, G. Henkelman
J. Phys. Chem. C, 2018, 122, 2712-2716.

2017 Publications

Highly Selective Adsorption of p-Xylene over other C8 Aromatic Hydrocarbons by Co-CUK-1: A Combined Experimental and Theoretical Assessment
J. W. Yoon, J. S. Lee, G. W. Piburn, K.-H. Cho, K. Jeon, H.-K. Lim, H. Kim, C.-H. Jun, S. M. Humphrey, R. Krishna, J. S. Chang
Dalton Trans., 2017, 46, 16096-16101.

Synthesis and Characterization of a Binuclear Copper(II) Naphthoisoamethyrin Complex Displaying Weak Antiferromagnetic Coupling
J. T. Brewster II, G. Anguera, M. D. Moore, B. S. Dolinar, H. Zafar, G. D. Thiabaud, V. M. Lynch, S. M. Humphrey, J. L. Sessler
Inorg. Chem., 2017, 56, 12665-12669.

Rapid Synthesis of RhPd Alloy Nanocatalysts
G. W. Piburn, H. Li, P. Kunal, G. Henkelman, S. M. Humphrey
ChemCatChem, 2017, 10, 329-333.

Magnetic Properties of the Distorted Kagomé Lattice Mn3(1,2,4-(O2C)3C6H3)2
R. A. Mole, S. Greene, P. F. Henry, S. M. Humphrey, K. C. Rule, T. Unruh, G. F. Weldon, D. Yu, J. A. Stride, P. T. Wood
Inorg. Chem., 2017, 56, 7851-7860.

Continuous Flow Synthesis of Rh and RhAg Alloy Nanoparticle Catalysts Enables Scalable Production and Improved Morphological Control
P. Kunal, E. J. Roberts, C. T. Riche, K. Jarvis, N. Malmstadt, R. J. Brutchey, S. M. Humphrey
Chem. Mater., 2017, 29, 4341-4350.

PdAu Alloy Nanoparticle Catalysts: Effective Candidates for Nitrite Reduction in Water
S. Seraj, P. Kunal, H. Li, G. Henkelman, S. M. Humphrey, C. J. Werth
ACS Catalysis, 2017, 7, 3268-3276.

A sensor for trace H2O detection in D2O
S. G. Dunning, A. J. Nunez, M. D. Moore, A. Steiner, V. M. Lynch, J. L. Sessler, B. J. Holliday, S. M. Humphrey
Chem, 2017, 2, 579-589.

Synthesis and charge storage properties of templated LaMnO3-SiO2 composite materials
G. W. Piburn, J. T. Mefford, N. Zinni, K. J. Stevenson, S. M. Humphrey
Dalton Trans., 2017, 46, 977-984.

2016 Publications

A PCP Pincer Ligand for Coordination Polymers with Versatile Chemical Reactivity: Selective Activation of CO2 Gas over CO Gas in the Solid State, J. He, N. W. Waggoner, S. G. Dunning, A. Steiner, V. M. Lynch, S. M. Humphrey, Angew. Chem. Int. Ed. 2016, 55, 12351-12355.

Microwave-​Assisted Synthesis of PdxAu100-​x Alloy Nanoparticles: A Combined Experimental and Theoretical Assessment of Synthetic and Compositional Effects upon Catalytic Reactivity, P. Kunal, H. Li, B. L. Dewing, L. Zhang, K. Jarvis, G. Henkelman, S. M. Humphrey, ACS Catalysis. 2016, 6, 4882-4893.

Ship in a breakable bottle: fluoride-induced release of an organic molecule from a Pr(III)-linked molecular cage, J. Lee, N. W. Waggonner, L. Polanco, G. R. You, V. M. Lynch, S. K. Kim, S. M. Humphrey, J. L. Sessler, Chem. Commun. 2016, 52, 8514-8517.

An unusual coordination polymer containing Cu+ ions and featuring possible Cu⋯Cu ‘cuprophilic’ interactions: poly[di-μ-chlorido-(μ4-3,5-diaminobenzoato-κ4O:O’:N:N’)tricopper(I)(3 Cu-Cu)] , M. K. Khosa, P. T. Wood, S. M. Humphrey, W. T. A. Harrison, Acta Cryst. 2016, C72, 63-67.

2015 Publications

Inelastic Neutron Scattering and Theoretical Studies of H2 Sorption in a Dy(III)-Based Phosphine Coordination Material, K. A. Forrest, T. Pham, P. A. Georgiev, J. P. Embs, N. W. Waggoner, A. Hogan, S. M. Humphrey, J. Eckert, B. Space, Chem. Mater. 2015, 27, 7619–7626.

Separation of p-divinylbenzene by selective room-temperature adsorption inside Mg-CUK-1 prepared by aqueous microwave synthesis, B. Saccoccia, A. M. Bohnsack, N. W. Waggonner, K-H. Cho, J-S. Lee, D-Y. Hong, J-S. Chang, S. M. Humphrey, Angew. Chem. Int. Ed. 2015, 54, 5394-5398.

Metal-Organic Frameworks as Chemical Sensors, N. W. Waggoner, A. M. Bohnsack, S. M. Humphrey, book chapter in Functional Supramolecular Materials, Royal Society of Chemistry, 2015. RSC Smart Materials, 2015, 15, 192-245.

2014 Publications

Magnetism of linear [Ln3]9+ oxo-bridged clusters (Ln = Pr, Nd) supported inside a [R3PR’]+ phosphonium coordination material, N. W. Waggoner, B. Saccoccia, I. A. Ibarra, V. M. Lynch, P. T. Wood, S. M. Humphrey, Inorg. Chem. 2014, 53, 12674-12676.

Microwave synthesis of classically immiscible rhodium-silver and rhodium-gold alloy nanoparticles: Highly active hydrogenation catalysts, S. Garcia, L. Zhang, G. W. Piburn, G. Henkelman, S. M. Humphrey, ACS Nano 2014, 8 11512-11521.

Microwave-assisted Synthesis of Metallic Nanoparticles, S. Garcia, G. W. Piburn, S. M. Humphrey, book chapter in Microwave Engineering of Materials and Nanomaterials, Pan Stanford Publishing, 2014.

Effect of microwave heating on the synthesis of rhodium nanoparticles in ionic liquids, S. Garcia, J. J. Buckley, R. L. Brutchey, S. M. Humphrey, Inorg. Chim. Acta 2014, 422, 65-69.

Li- and Na-reduction products of meso-Co3O4 form high-rate, stably cycling battery anode materials, K. C. Klavetter, S. Garcia, N. Dahal, J. L. Snider, J. P. de Souza, T. H. Cell, M. A. Cassara, A. Heller, S. M. Humphrey, C. B. Mullins, J. Mater. Chem. A 2014, 2, 14209.

Bis(imino)acenaphthene (BIAN)-supported palladium(II) carbene complexes as effective C-C coupling catalysts and solvent effects in organic and aqueous media, K. A. Crawford, A. H. Cowley, S. M. Humphrey, Catal. Sci. Technol. 2014, 4, 1456.

Tuning the Host-Guest Interactions in a Phosphine Coordination Polymer Through Different Types of Post-Synthetic Modification, A. J. Nuñez, Maxwell S. Chang, I. A. Ibarra, S. M. Humphrey, Inorg. Chem. 2014, 53, 282.

2013 Publications

Rational Design of Porous Coordination Polymers Based on Bis(phosphine)MCl2 Compelxes That Exhibit High-Temperature H2 Sorption and Chemical Reactivity, A. M. Bohnsack, I. A. Ibarra, V. I. Bakhmutov, V. M. Lynch, S. M. Humphrey, J. Am. Chem. Soc. 2013, 135, 16038-16041.

Rhenium(I) Phenanthrolines Bearing Electron Withdrawing CF3 Substituents: Sythesis, Characterization and Biological Evaluation, C. Redshaw, S. Watkins, S. M. Humphrey, P. C. B. Page, S. Ashby, Y. Chao, C. J. Herbert, A. Müller RSC Advances 2012, 3, 23963-23966.

Molecular Sensing and Discrimination by a Luminescent Terbium-Phosphine Oxide Coordination Material, I. A. Ibarra, T. W. Hesterberg, J. Chang, J. W. Yoon, B. J. Holliday, S. M. Humphrey, Chem. Commun. 2013, 49, 7156-7158.

Microwave Synthesis of Au-Rh Core-Shell Nanparticles and Implications of the Shell Thickness in Hydrogenation Catalysis, S. García, N. Dahal, J. Zhou, H. Celio, A. Dolocan, S. M. Humphrey, Chem Commun. 2013, 49, 4241.

New Structural Motifs in Lithium and Zinc Calix[4]arene Chemistry, C. Redshaw, O. Rowe, D. L. Hughes, A. Fuller, I. A. Ibarra, and S. M. Humphrey, Dalton Trans. 2013, 42, 1983.

2012 Publications

Beneficial Effects of Microwave-Assisted Heating versus Conventional Heating in Noble Metal Nanoparticle Synthesis, N. Dahal, S. García, J. Zhou, S. M. Humphrey, ACS Nano. 2012.

Organic Vapor Sorption in a High Surface Area Dysprosium(III)-Phosphine Oxide Coordination Material, I. A. Ibarra, J. W. Yoon, J.-S. Chang, S.-K. Lee, V. M. Lynch, S. M. Humphrey, Inorg. Chem. 2012.

Gas Sorption and Luminescence properties of a Terbium(III)-Phosphine Oxide Coordination Material with Two-Dimensional Pore Topology, Ibarra, I. A., Hesterberg, T. W., Holliday, B. D., Lynch, V. M., Humphrey, S. M., Dalton Trans. 2012, 41, 3920.

High Surface Area Mesoporous Co3O4 from a Direct Soft-Template Route, N. Dahal, I. A. Ibarra, S. M. Humphrey, J. Mater. Chem. 2012, 22, 12675.

CO2 adsorption properties of a Ca(II)-based organophosphonium coordination material, I. A. Ibarra, K. E. Tan, V. M. Lynch, S. M. Humphrey, Dalton Trans. 2012, 41, 3920.

2011 Publications

A Coordination Polymer of (Ph3P)AuCl Prepared by Post-Synthetic Modification and its Application in 1-Hexene/n-Hexane Separation, A. J. Nuñez, L. N. Shear, N. Dahal, I. A. Ibarra, J. W. Yoon, J.-S. Chang, S. M. Humphrey, Chem. Commun. 2011, 47, 11855.

High capacity CO2 adsorption in a Mg(II)-based phosphine oxide coordination material, A. M. Bohnsack, I. A. Ibarra, P. W. Hatfield, Y. K. Hwang, J. W. Yoon, J.-S. Chang, S. M. Humphrey, Chem. Commun. 2011, 47, 4899.

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