Publications Old Page

2021 Publications

Sequential Post-Synthetic Modifications to a Phosphine Selenide Metal-Organic Framework: Removal of Se Protecting Group and Subsequent Coordination of Au(I) and Ag(I) to P(III) Sites S. L. White, V. Lynch, S. G. Dunning, S. M. Humphrey In Progress, 2021.
Investigating H2 Sorption in Isostructural Metal-Organic Frameworks M-CUK-1 (M = Co, Mg) Through Experimental and Theoretical Studies S. Suepaul, K. A. Forrest, P. A. Georgiev, P. M. Forster, W. Lohstroh, V. Grzimek, S. G. Dunning, J. E. Reynolds III, S. M. Humphrey, J. Eckert, B. Space, T. Pham Submitted, 2021.
Low-Valent Metal Ions as MOF Pillars: A New Route Toward Stable and Multifunctional MOFs R. E. Sikma, N. Katyal, S. Lee, J. W. Fryer, C. G. Romero, S. K. Emslie, E. Taylor, V. M. Lynch, J.-S. Chang, G. Henkelman, S. M. Humphrey J. Am. Chem. Soc., 2021, 143, 13710-13720.
Magnetism and Luminescence of a MOF with Linear Mn3 Nodes Derived from an Emissive Terthiophene-Based Imidazole Linker W. Wang, J. He, H. Guo, S. G. Dunning, S. M. Humphrey, R. A. Jones Molecules, 2021, 26(14), 4286. – Alan H. Cowley Memorial Edition.
Methods and Diversity in the Synthesis of Metal-Organic Frameworks S. L. White, M. W. Heinz, S. M. Humphrey Book Chapter in Comprehensive Coordination Chemistry III, Elsevier, 2021.

2020 Publications

Organometallic Chemistry at Various Length Scales: More Than Just Metal-Carbon Bonds Bring Chemists Together D. J. Mindiola, M. Delferro, S. M. Humphrey Organometallics, 2020, 39, 881-882.
PdxAuyCu(100-x-y) Ternary Alloy Nanoparticles: Highly Tunable and Economical Reduction Catalysis P. Kunal, H. Guo, C. Yan, H. Li, S. G. Dunning, M. Duncan, K. Jarvis, C. J. Werth, G. Henkelman, S. M. Humphrey Submitted.
PdAg Alloy Nanocatalysts: Toward Economically Viable Nitrite Reduction in Drinking Water J. P. Troutman, H. Li, A. M. Haddix, B. A. Kienzle, G. Henkelman, S. M. Humphrey, C. J. Werth ACS Catal, 2020, 10, 7979–7989.
CuxIr(1-x) Nanoalloy Catalyts Achieve Near 100% Selectivity for Aqueous Nitrite Reduction to NH3 Selectivity H. Li, C. Yan, H. Guo, K. Shin, S. M. Humphrey, C. J. Werth, G. Henkelman ACS Catal., 2020, 10, 7915–7921.
Testing the Predictive Power of Theory for PdxIr(100‒x) Alloy Nanoparticles for the Oxygen Reduction Reaction H. Guo, J. Trindell, H. Li, D. Fernandez, S. M. Humphrey, G. Henkelman, R. Crooks J. Mater. Chem. A, 2020, 8421-8429.
Hydro­thermal synthesis and crystal structure of poly[bis­(μ3-3,4-di­amino­benzoato)manganese], a layered coordination polymer M. K. Khosa, P. T. Wood, S. M. Humphrey, W. T. A. Harrison Acta Cryst., 2020, E76, 909-913.
Reversible Solid-State Isomerism by Azobenzene-Loaded Large-Pore Isoreticular Mg-CUK-1 J. He, K. Aggarwal, N. Katyal, S. He, E. Chiang, S. G. Dunning, J. E. Reynolds III, A. Steiner, G. Henkelman, E. Que, S. M. Humphrey J. Am. Chem. Soc., 2020, 142, 6467-6471.
In situ formation of a triselenane NSeN-pincer MOF and single-crystal-to-single-crystal oxidation S. He, L. L. Allemond, S. G. Dunning, J. E. Reynolds III, V. M. Lynch, S. M. Humphrey Chem. Commun., 2020, 56, 1286-1289.
Hydrogen Evolution by Ni2P Catalysts Derived from Phosphine MOFs O. Mabayoje, S. G. Dunning, B. Wygant, R. Ciufo, K. Kawashima, S. M. Humphrey, C. B. Mullins ACS Appl. Energy Mater., 2020, 3, 176-183.

2019 Publications

Stabilizer-Free CuIr Alloy Nanoparticle Catalysts H. Guo, H. Li, D. Fernandez, S. Willis, K. Jarvis, G. Henkelman, S. M. Humphrey Chem. Mater., 2019, 31, 10225-10235.
Rational Design of Rhodium-​Iridium Alloy Nanoparticles as Highly Active Catalysts for Acidic Oxygen Evolution H. Guo, Z. Fang, H. Li, D. Fernandez, G. Henkelman, S. M. Humphrey, G. Yu ACS Nano, 2019, 13, 13225-13234.
Dipyrrolylnaphthyridine-based Schiff-base cryptands and their selective gas adsorption properties F. Wang, R. E. Sikma, Z. Duan, C. Lei, Z. Zhang, S. M. Humphrey, J. L. Sessler J. Porphyr. Phthalocya., 2019, 24, 424-431.
Accumulation-Driven Unified Spatiotemporal Synthesis and Structuring of Immiscible Metallic Nanoalloys B. B. Rajeeva, P. Kunal, P. S. Kollipara, P. V. Acharya, M. Joe, M. S. Ide, K. Jarvis, Y. Liu, V. Bahadur, S. M. Humphrey, Y. Zheng Matter, 2019, 1, 1606-1617.
Direct, One-Pot Syntheses of MOFs Decorated with Low-Valent Metal-Phosphine Complexes S. G. Dunning, J. E. Reynolds III, K. M. Walsh, D. J. Kristek, V. M. Lynch, P. Kunal, S. M. Humphrey Organometallics, 2019, 38, 3406-3411.
Porous Metal–Organic Framework CUK-1 for Adsorption Heat Allocation toward Green Applications of Natural Refrigerant Water J. S. Lee, J. W. Yoon, P. G. M. Mileo, K. H. Cho, J. Park, H. Kim, M. F. de Lange, F. Kapteijn, G. Maurin, S. M. Humphrey, J.-S. Chang ACS App. Mater. Interfaces, 2019, 11, 25778-25789.
Phosphonium zwitterions for lighter and chemically-robust MOFs: Highly reversible H2S capture and solvent-triggered release J. E. Reynolds III, A. M. Bohnsack, D. J. Kristek, A. Gutiérrez-Alejandre, S. G. Dunning, N. W. Waggoner, R. E. Sikma, I. A. Ibarra, S. M. Humphrey J. Mater. Chem. A, 2019, 7, 16842-16849.
Shape-persistent pyrrole-based covalent organic cages: Synthesis, structure and selective gas adsorption properties F. Wan, R. E. Sikma, Z. Duan, T. Sarma, C. Lei, Z. Zhang, S. M. Humphrey, J. L. Sessler Chem. Commun., 2019, 55, 6185-6188.

2018 Publications

Humidity-induced CO2 capture enhancement in Mg-CUK-1 M. Sagastuy-Breña, P. G. M. Mileo, E. Sánchez-González, J. E. Reynolds, III, T. Jurado-Vázquez, J. Balmaseda, E. González-Zamora, S. Devautour-Vinot, S. M. Humphrey, G. Maurin, I. A. Ibarra Dalton Trans., 2018, 47, 15827-15834.
Structural Characterization of Heterogeneous Rh-Au Nanoparticles from a Microwave-Assisted Synthesis Z. Duan, J. Timoschenko, P. Kunal, S. House, H. Wan, K. Jarvis, C. Bonifacio, J. C. Yang, R. M. Crooks, A. I. Frenkel, S. M. Humphrey, G. Henkelman Nanoscale, 2018, 10, 22520-22532.
Highly Selective Room Temperature Acetylene Sorption by an Unusual Triacetylenic Phosphine MOF J. E. Reynolds III, K. M. Walsh, B. Li, P. Kunal, B. Chen, S. M. Humphrey Chem. Commun., 2018, 54, 9937-9940.
An Organoarsine MOF with cis-Diarsine Pockets for the Installation of Uniquely Confined Metal Complexes R. E. Sikma, P. Kunal, S. G. Dunning, J. E. Reynolds III, J.-S. Lee, J.-S. Chang, S. M. Humphrey J. Am. Chem. Soc., 2018, 140, 9806-9809.
Microwave-Assisted Synthesis of Classically Immiscible Ag–Ir Alloy Nanoparticle Catalysts H. Guo, H. Li, K. Jarvis, H. Wan, P. Kunal, S. G. Dunning, Y. Liu, G. Henkelman, S. M. Humphrey ACS Catal., 2018, 8, 11386-11397.
Highly reversible sorption of H2S and CO2 by an environmentally-friendly Mg-based MOF E. Sánchez-González, P. G. M. Mileo, M. Sagastuy-Breña, J. R. Álvarez, J. E. Reynolds III, A. Villarreal, A. Gutiérrez-Alejandre, J. Ramírez, J. Balmaseda, E. González-Zamora, G. Maurin, S. M. Humphrey, I. A. Ibarra J. Mater. Chem. A, 2018, 6, 16900-16909.
Optothermophoretic Manipulation of Colloidal Particles in Nonionic Liquids X. Peng, L. Lin, E. H. Hill, P. Kunal, S. M. Humphrey, and Y. Zheng J. Phys. Chem. C, 2018, Accepted. DOI:10.1021/acs.jpcc.8b03828
A MOF with Cooperative Phosphines that Permits Post‐Synthetic Installation of Open Metal Sites S. G. Dunning, G. Nandra, A. D. Conn, W. Chai, R. E. Sikma, J.-S. Lee, P. Kunal, J. E. Reynolds III, J.-S. Chang, A. Steiner, G. Henkelman, S. M. Humphrey Angew. Chem. Int. Ed., 2018, 57, 9295-9299.
1-D and 2-D Phosphine Coordination Materials based on a Palladium(II) PCP Pincer Metalloligand J. He, A. M. Bohnsack, N. W. Waggoner, S. G. Dunning, V. M. Lynch, W. C. Kaska, S. M. Humphrey Polyhedron, 2018, 143, 149-156.
A Survey of Metal-Organic Frameworks Based on Phosphorus- and Sulfur-Containing Building Blocks J. E. Reynolds III, S. G. Dunning, C. M. McCulley, S. M. Humphrey, Book chapter in Elaboration and Applications of Metal-Organic Frameworks, World Scientific, 2018.
Oxygen Reduction Reaction on Classically Immiscible Bimetallics: A Case Study of RhAu H. Li, L. Luo, P. Kunal, C. S. Bonifacio, Z. Duan, J. Yang, S. M. Humphrey, R. M. Crooks, G. Henkelman J. Phys. Chem. C, 2018, 122, 2712-2716.

2017 Publications

Highly Selective Adsorption of p-Xylene over other C8 Aromatic Hydrocarbons by Co-CUK-1: A Combined Experimental and Theoretical Assessment J. W. Yoon, J. S. Lee, G. W. Piburn, K.-H. Cho, K. Jeon, H.-K. Lim, H. Kim, C.-H. Jun, S. M. Humphrey, R. Krishna, J. S. Chang Dalton Trans., 2017, 46, 16096-16101.
Synthesis and Characterization of a Binuclear Copper(II) Naphthoisoamethyrin Complex Displaying Weak Antiferromagnetic Coupling J. T. Brewster II, G. Anguera, M. D. Moore, B. S. Dolinar, H. Zafar, G. D. Thiabaud, V. M. Lynch, S. M. Humphrey, J. L. Sessler Inorg. Chem., 2017, 56, 12665-12669.
Rapid Synthesis of RhPd Alloy Nanocatalysts G. W. Piburn, H. Li, P. Kunal, G. Henkelman, S. M. Humphrey ChemCatChem, 2017, 10, 329-333.
Magnetic Properties of the Distorted Kagomé Lattice Mn3(1,2,4-(O2C)3C6H3)2 R. A. Mole, S. Greene, P. F. Henry, S. M. Humphrey, K. C. Rule, T. Unruh, G. F. Weldon, D. Yu, J. A. Stride, P. T. Wood Inorg. Chem., 2017, 56, 7851-7860.
Continuous Flow Synthesis of Rh and RhAg Alloy Nanoparticle Catalysts Enables Scalable Production and Improved Morphological Control P. Kunal, E. J. Roberts, C. T. Riche, K. Jarvis, N. Malmstadt, R. J. Brutchey, S. M. Humphrey Chem. Mater., 2017, 29, 4341-4350.
PdAu Alloy Nanoparticle Catalysts: Effective Candidates for Nitrite Reduction in Water S. Seraj, P. Kunal, H. Li, G. Henkelman, S. M. Humphrey, C. J. Werth ACS Catalysis, 2017, 7, 3268-3276.
A sensor for trace H2O detection in D2O S. G. Dunning, A. J. Nunez, M. D. Moore, A. Steiner, V. M. Lynch, J. L. Sessler, B. J. Holliday, S. M. Humphrey Chem, 2017, 2, 579-589.
Synthesis and charge storage properties of templated LaMnO3-SiO2 composite materials G. W. Piburn, J. T. Mefford, N. Zinni, K. J. Stevenson, S. M. Humphrey Dalton Trans., 2017, 46, 977-984.

2016 Publications

A PCP Pincer Ligand for Coordination Polymers with Versatile Chemical Reactivity: Selective Activation of CO₂ Gas over CO Gas in the Solid State, J. He, N. W. Waggoner, S. G. Dunning, A. Steiner, V. M. Lynch, S. M. Humphrey, Angew. Chem. Int. Ed. 2016, 55, 12351-12355.

Microwave-​Assisted Synthesis of Pd_xAu_100-​x Alloy Nanoparticles: A Combined Experimental and Theoretical Assessment of Synthetic and Compositional Effects upon Catalytic Reactivity, P. Kunal, H. Li, B. L. Dewing, L. Zhang, K. Jarvis, G. Henkelman, S. M. Humphrey, ACS Catalysis. 2016, 6, 4882-4893.

Ship in a breakable bottle: fluoride-induced release of an organic molecule from a Pr(III)-linked molecular cage, J. Lee, N. W. Waggonner, L. Polanco, G. R. You, V. M. Lynch, S. K. Kim, S. M. Humphrey, J. L. Sessler, Chem. Commun. 2016, 52, 8514-8517.

An unusual coordination polymer containing Cu⁺ ions and featuring possible Cu⋯Cu ‘cuprophilic’ interactions: poly[di-μ-chlorido-(μ₄-3,5-diaminobenzoato-κ⁴O:O’:N:N’)tricopper(I)(3 Cu-Cu)] , M. K. Khosa, P. T. Wood, S. M. Humphrey, W. T. A. Harrison, Acta Cryst. 2016, C72, 63-67.

2015 Publications

Inelastic Neutron Scattering and Theoretical Studies of H2 Sorption in a Dy(III)-Based Phosphine Coordination Material, K. A. Forrest, T. Pham, P. A. Georgiev, J. P. Embs, N. W. Waggoner, A. Hogan, S. M. Humphrey, J. Eckert, B. Space, Chem. Mater. 2015, 27, 7619–7626.

Separation of p-divinylbenzene by selective room-temperature adsorption inside Mg-CUK-1 prepared by aqueous microwave synthesis, B. Saccoccia, A. M. Bohnsack, N. W. Waggonner, K-H. Cho, J-S. Lee, D-Y. Hong, J-S. Chang, S. M. Humphrey, Angew. Chem. Int. Ed. 2015, 54, 5394-5398.

Metal-Organic Frameworks as Chemical Sensors, N. W. Waggoner, A. M. Bohnsack, S. M. Humphrey, book chapter in Functional Supramolecular Materials, Royal Society of Chemistry, 2015. RSC Smart Materials, 2015, 15, 192-245.

2014 Publications

Magnetism of linear [Ln₃]⁹⁺ oxo-bridged clusters (Ln = Pr, Nd) supported inside a [R₃PR’]⁺ phosphonium coordination material, N. W. Waggoner, B. Saccoccia, I. A. Ibarra, V. M. Lynch, P. T. Wood, S. M. Humphrey, Inorg. Chem. 2014, 53, 12674-12676.

Microwave synthesis of classically immiscible rhodium-silver and rhodium-gold alloy nanoparticles: Highly active hydrogenation catalysts, S. Garcia, L. Zhang, G. W. Piburn, G. Henkelman, S. M. Humphrey, ACS Nano 2014, 8 11512-11521.

Microwave-assisted Synthesis of Metallic Nanoparticles, S. Garcia, G. W. Piburn, S. M. Humphrey, book chapter in Microwave Engineering of Materials and Nanomaterials, Pan Stanford Publishing, 2014.

Effect of microwave heating on the synthesis of rhodium nanoparticles in ionic liquids, S. Garcia, J. J. Buckley, R. L. Brutchey, S. M. Humphrey, Inorg. Chim. Acta 2014, 422, 65-69.

Li- and Na-reduction products of meso-Co₃O₄ form high-rate, stably cycling battery anode materials, K. C. Klavetter, S. Garcia, N. Dahal, J. L. Snider, J. P. de Souza, T. H. Cell, M. A. Cassara, A. Heller, S. M. Humphrey, C. B. Mullins, J. Mater. Chem. A 2014, 2, 14209.

Bis(imino)acenaphthene (BIAN)-supported palladium(II) carbene complexes as effective C-C coupling catalysts and solvent effects in organic and aqueous media, K. A. Crawford, A. H. Cowley, S. M. Humphrey, Catal. Sci. Technol. 2014, 4, 1456.

Tuning the Host-Guest Interactions in a Phosphine Coordination Polymer Through Different Types of Post-Synthetic Modification, A. J. Nuñez, Maxwell S. Chang, I. A. Ibarra, S. M. Humphrey, Inorg. Chem. 2014, 53, 282.

2013 Publications

Rational Design of Porous Coordination Polymers Based on Bis(phosphine)MCl₂ Compelxes That Exhibit High-Temperature H₂ Sorption and Chemical Reactivity, A. M. Bohnsack, I. A. Ibarra, V. I. Bakhmutov, V. M. Lynch, S. M. Humphrey, J. Am. Chem. Soc. 2013, 135, 16038-16041.

Rhenium(I) Phenanthrolines Bearing Electron Withdrawing CF₃ Substituents: Sythesis, Characterization and Biological Evaluation, C. Redshaw, S. Watkins, S. M. Humphrey, P. C. B. Page, S. Ashby, Y. Chao, C. J. Herbert, A. Müller RSC Advances 2012, 3, 23963-23966.

Molecular Sensing and Discrimination by a Luminescent Terbium-Phosphine Oxide Coordination Material, I. A. Ibarra, T. W. Hesterberg, J. Chang, J. W. Yoon, B. J. Holliday, S. M. Humphrey, Chem. Commun. 2013, 49, 7156-7158.

Microwave Synthesis of Au-Rh Core-Shell Nanparticles and Implications of the Shell Thickness in Hydrogenation Catalysis, S. García, N. Dahal, J. Zhou, H. Celio, A. Dolocan, S. M. Humphrey, Chem Commun. 2013, 49, 4241.

New Structural Motifs in Lithium and Zinc Calix[4]arene Chemistry, C. Redshaw, O. Rowe, D. L. Hughes, A. Fuller, I. A. Ibarra, and S. M. Humphrey, Dalton Trans. 2013, 42, 1983.

2012 Publications

Beneficial Effects of Microwave-Assisted Heating versus Conventional Heating in Noble Metal Nanoparticle Synthesis, N. Dahal, S. García, J. Zhou, S. M. Humphrey, ACS Nano. 2012.

Organic Vapor Sorption in a High Surface Area Dysprosium(III)-Phosphine Oxide Coordination Material, I. A. Ibarra, J. W. Yoon, J.-S. Chang, S.-K. Lee, V. M. Lynch, S. M. Humphrey, Inorg. Chem. 2012.

Gas Sorption and Luminescence properties of a Terbium(III)-Phosphine Oxide Coordination Material with Two-Dimensional Pore Topology, Ibarra, I. A., Hesterberg, T. W., Holliday, B. D., Lynch, V. M., Humphrey, S. M., Dalton Trans. 2012, 41, 3920.

High Surface Area Mesoporous Co₃O₄ from a Direct Soft-Template Route, N. Dahal, I. A. Ibarra, S. M. Humphrey, J. Mater. Chem. 2012, 22, 12675.

CO₂ adsorption properties of a Ca(II)-based organophosphonium coordination material, I. A. Ibarra, K. E. Tan, V. M. Lynch, S. M. Humphrey, Dalton Trans. 2012, 41, 3920.

2011 Publications

A Coordination Polymer of (Ph₃P)AuCl Prepared by Post-Synthetic Modification and its Application in 1-Hexene/n-Hexane Separation, A. J. Nuñez, L. N. Shear, N. Dahal, I. A. Ibarra, J. W. Yoon, J.-S. Chang, S. M. Humphrey, Chem. Commun. 2011, 47, 11855.

High capacity CO₂ adsorption in a Mg(II)-based phosphine oxide coordination material, A. M. Bohnsack, I. A. Ibarra, P. W. Hatfield, Y. K. Hwang, J. W. Yoon, J.-S. Chang, S. M. Humphrey, Chem. Commun. 2011, 47, 4899.

Older Publications

• Sonagashira coupling catalyzed by gold nanoparticles: does homogeneous or heterogeneous catalysis dominate?, G. Kyriahou, S. K. Beaumont, S. M. Humphrey, C. Antonetti, R. M. Lambert, ChemCatChem, 2010, 2, 1444.
• Mixed Alkali Metal/Transition Metal Coordination Polymers with the Mellitic Acid Hexaanion: 2-Dimensional Hexagonal Magnetic Nets, S. M. Humphrey, R. A. Mole, R. I. Thompson, P. T. Wood, Inorg. Chem. 2010, 49, 3441.
• Pyridine-2,4-Dicarboxylate: A Versatile Building Block for the Preparation of Functional Coordination Polymers, S. M. Humphrey, G. F. Weldon, P. T. Wood, J. Nanosci. Nanotech. 2010, 10, 34.
• Evidence for Heterogeneous Sonogashira Coupling of Phenylacetylene and Iodobenzene Catalyzed by Well Defined Rhodium Nanoparticles, V. K. Kanuru, S. M. Humphrey, J. M. W. Kyffin, D. A. Jefferson, J. Burton, R. M. Lambert, Dalton Trans. 2009, 7602.
• Metal-Organophosphine and Metal-Organophosphonium Frameworks with Layered Honeycomb-like Structures, S. M. Humphrey, P. K. Allan, S. E. Oungoulian, M. S. Ironside, E. R. Wise, Dalton Trans. 2009, 2298.
• Hysteretic Sorption of Light Gases by a Porous Metal-Organic Framework Containing Tris(­p­-Carboxylated) Triphenylphosphine Oxide, S. M. Humphrey, S. E. Oungoulian, Y. K. Hwang, E. R. Wise, J. W. Yoong, J.-S. Chang, Chem. Commun. 2008, 2891.
• A Tin(II)-Containing Ansa-Tris(allyl) ligand and its Potassium Complex, R. A. Layfield, F. García, J. Hannauer, S. M. Humphrey, Chem. Commun. 2007, 5081.
• Bimetallic Metal-Organic Frameworks Containing the [M(2,x-pdc)₂]^2- (M = Cu, Pd, Pt; x = 4,5) Building Block: Synthesis, Structure and Magnetic Properties, S. M. Humphrey, T. J. P. Angliss, M. Aransay, D. Cave, L. A. Gerrard, G. F. Weldon, P. T. Wood, Zeit. Anorg. Allg. Chem. 2007, 633, 2342.
• Gas-Sorption Selectivity on a Porous Coordination Solid of Co(II), CUK-1, J. W. Yoon, S. H. Jhung, Y. K. Hwang, S. M. Humphrey, P. T. Wood, J.-S. Chang , Adv. Mater. 2007, 19, 1830.
• The Synthesis, Structure and Reactivity of B(C₆F­₅)₃-Stabilised Amide (M-NH₂) Complexes of the Group 4 Metals, A. J. Mountford, W. Clegg, S. J. Coles, R. W. Harrington, P. N. Horton, S. M. Humphrey, M. B. Hursthouse, J. A. Wright, S. J. Lancaster, Chem. Eur. J. 2007, 13, 4535.
• Charge-Transfer Interaction of Poly(vinylpyrrolidone) with Platinum and Rhodium Nanoparticles, Y. Borodko, S. M. Humphrey, T. D. Tilley, H. Frei, G. A. Somorjai, J. Phys. Chem. C. 2007, 111, 6288.
• Rhodium Nanoparticles from Cluster Seeds: Control of Size and Shape by Precursor Addition Rate, S. M. Humphrey, M. E. Grass, S. E. Habas, K. Niesz, G. A. Somorjai, T. D. Tilley, Nano Lett. 2007, 7, 785.
• Porous Cobalt(II)-Organic Frameworks with Corrugated Walls: Robust Gas-Sorption Materials, S. M. Humphrey, J.-S. Chang, S. H. Jhung, J. W. Yoon, P. T. Wood, Angew. Chem., Int. Ed. 2007, 46, 272.
• The Cationic Cluster Grignard [{MgCl(thf)₂}₃(η₃-C₃H₅)₂]⁺, R. A. Layfield, T. H. Bullock, F. García, S. M. Humphrey, P. Schüler, Chem. Commun. 2006, 2039.
• A New Co(II) Coordination Solid with Mixed Oxygen, Carboxylate, Pyridine and Thiolate Donors Exhibiting Canted Antiferromagnetism with T_c ≈ 68 K, S. M. Humphrey, A. Alberola, C. J. Gómez García, P. T. Wood, Chem. Commun. 2006, 1607.
• Complexes of Tungsten(IV,VI) Derived from Linked Aryloxide Ligands, C. Redshaw, S. M. Humphrey, Polyhedron 2006, 25, 1946.
• Spin Transitions in a Dithiazolyl Radical: Preparation, Crystal Structures and Magnetic Properties of 3-Cyanobenzo-1,2,3-dithiazolyl, C₇H₃S₂N₂•, A. Alberola, R. J. Collis, S. M. Humphrey, R. J. Less, J. M. Rawson, Inorg. Chem. 2006, 45, 1903.
• Ligand Transfer Reactions of Mixed-Metal Lanthanide/Magnesium Allyl Complexes with b-Diketimines: Synthesis, Structures, and Ring-Opening polymerization Catalysis, L. F. Sánchez-Barba, D. L. Hughes, S. M. Humphrey, M. Bochmann, Organometallics, 2006, 25, 1012.
• Titanium, Zinc and Alkaline-Earth Metal Complexes Supported by Bulky O,N,N,O-Multidentate Ligands: Synthesis, Characterisation and Activity in Cyclic Ester Polymerisation, Y. Sarazin, R. H. Howard, D. L. Hughes, S. M. Humphrey, M. Bochmann, Dalton Trans. 2006, 340.
• EPR Studies on the Thiophenodithiazolyl radical, C₄H₂S₃N•, A. Alberola, R. D. Farley, S. M. Humphrey, G. D. McManus, D. M. Murphy, J. M. Rawson, Dalton Trans. 2005, 3838.
• Synthesis and Structure of [trans-{1,2-Bis(η²-O,N,N-phenylcarbamoyl)cyclopentadienyl bis(thf)} magnesium]·4thf, R. A. Layfield, S. M. Humphrey, Organometallics 2005, 24, 6063.
• Synthesis and Structures of New Mixed-Metal Lanthanide/Magnesium Allyl Complexes, L. F. Sánchez-Barba, D. L. Hughes, S. M. Humphrey, M. Bochmann, Organometallics 2005, 24, 5329.
• Isolated Magnetic Clusters of Co(II) and Ni(II) within 3-Dimensional Organic Frameworks of 6-Mercaptonicotinic Acid: Unique Structural Topologies Based on Selectivity for Hard and Soft Coordination Environments, S. M. Humphrey, R. A. Mole, M. McPartlin, E. J. L. McInnes, P. T. Wood, Inorg. Chem. 2005, 44, 5981.
• New Bis(allyl)(diketiminato) and Tris(allyl) Lanthanide Complexes and Their Reactivity in the Polymerization of Polar Monomers, L. F. Sánchez-Barba, D. L. Hughes, S. M. Humphrey, M. Bochmann, Organometallics 2005, 24, 3792.
• Quadruple Deprotonation of 2-Aminophenylphosphane with a p-Block-Metal/Alkali-Metal Base, F. García, S. M. Humphrey, R. A. Kowenicki, E. J. L. McInnes, C. M. Pask, M. McPartlin, J. M. Rawson, M. L. Stead, A. D. Woods, D. S. Wright, Angew. Chem., Int. Ed. 2005, 44, 3456.
• New Titanium and Zirconium Complexes with M-NH₂ Bonds Formed by Facile Deprotonation with H₃N·B(C₆F₅)₃, A. J. Mountford, W. Clegg, R. W. Harrington, S. M. Humphrey. S. J. Lancaster, Chem. Commun. 2005, 2044.
• Variable Solid State Aggregations in a Series of (Isocyanide)Gold(I) Halides with the Novel Trimethylamine-Isocyanoborane Adduct, S. M. Humphrey, H-G. Mack, C. Redshaw, M. R. J. Elsegood, K. J. H. Young, H. A. Mayer, W. C. Kaska, Dalton Trans. 2005, 439.
• Synthesis, Ion Aggregation, Alkyl Bonding Modes, and Dynamics of 14-Electron Matallocenium Ion Pairs [(SBI)MCH₂SiMe₃⁺···X^–] (M = Zr, Hf): Inner-Sphere (X = MeB(C₆F₅)₃) Structures versus Outer-Sphere (X = B(C₆F₅)₄) Structures and the Implications for “Continuous” or “intermittent” Alkene Polymerization Mechanisms, F. Song, S. J. Lancaster, R. D. Cannon, M. Schormann, S. M. Humphrey, C. Zuccaccia, A. Macchioni, M. Bochmann, Organometallics 2005, 24, 1315.
• Highly Selective Epoxidation of Styrene using a Transition Metal-Aluminium(III) Complex Containing the [MeAl(2-py)₃]^– Anion (2-py = 2-pyridyl), C. Soria Alvarez, F. García, S. M. Humphrey, A. D. Hopkins, R. A. Kowenicki, M. McPartlin, R. A. Layfield, R. Raja, M. C. Rogers, A. D. Woods, D. S. Wright, Chem. Commun. 2005, 198.
• Acid/Amide Bonding for Anthranilic Acid Derivatives: Crystal Structures [W(X)Cl3(HO₂CC₆H₄NH-2)] (X = O, NPh), S. M. Humphrey, C. Redshaw, K. E. Holmes, M. R. J. Elsegood, Inorg. Chim. Acta 2005, 358, 222.
• Synthesis and Structure of [{Sn₂(η-PMes)₃}K₂·3THF}_∞, Exhibiting Multifunctional Coordination of [Sn₂(m-PMes)₃]^2- Anions to K⁺, F. García, A. D. Hopkins, S. M. Humphrey, M. McPartlin, C. M. Pask, A. D. Woods, D. S. Wright, Organometallics 2004, 23, 4821.
• Multiple Areas of Magnetic Bistability in the Topological Ferrimagnet [Co₃(NC₅H₃(CO₂)₂-2,5)₂(μ₃-OH)₂(OH₂)₂], S. M. Humphrey, P. T. Wood, J. Am. Chem. Soc. 2004, 126, 13236.
• Syntheses, Structures, and Magnetic Properties of Mn(II) Dimers [CpMn(-X)]₂ (Cp = C₅H₅; RNH, R¹R²N, C≡CR), C. Soria Alvaraz, S. R. Boss, J. C. Burley, S. M. Humphrey, R. A. Layfield, R. A. Kowenicki, M. McPartlin, J. M. Rawson, A. E. H. Wheatley, P. T. Wood, D. S. Wright, Dalton Trans. 2004, 3481.
• [{H₃C)₃NB(H)₂NC}₂Au][AuI₂]: A Linear Chain Polymer of Gold(I) Iodide with an Unusual Isocyanoborane Ligand Showing Aurophilic Behaviour, W. C. Kaska, H. A. Mayer, M. R. J. Elsegood, P. N. Horton, M. B. Hursthouse, C. Redshaw, S. M. Humphrey, Acta Cryst. 2004, E60, m563.
• A Manganese(II) Allyl Complex: Synthesis, Structure and Magnetic Properties of [Li(thf)₄][Mn{η³-(Me₃Si)₂C₃H₃}{η¹-(Me₃Si)₂C₃H₃}₂], R. A. Layfield, S. M. Humphrey, Angew. Chem., Int. Ed. 2004, 43, 3067.
• Hydrothermal Synthesis and Magnetic Properties of Novel Mn(II) and Zn(II) Materials with Thiolato-Carboxylate Donor Ligand Frameworks, S. M. Humphrey, R. A. Mole, J. M. Rawson, P. T. Wood, Dalton Trans. 2004, 1670.
• Selective Formation of the [PhP(H)-PPh]^– Anion in the Reaction of PhPHLi with MeAlCl₂: Synthesis and Structure of the Unusual Tetramer [{PhP(H)-PPh}Li·thf]₄, F. García, S. M. Humphrey, R. A. Kowenicki, M. McPartlin, D. S. Wright, Dalton Trans. 2004, 977.
• Steric Control in the Oligomerization of Phosphazene Dimers; Towards New Phosphorus-Nitrogen Macrocycles, E. L. Doyle, F. García, S. M. Humphrey, R. A. Kowenicki, L. Riera, A. D. Woods, D. S. Wright, Dalton Trans. 2004, 807.
• The First Example of a Si-Bridged Tris(pyridyl) Ligand; Synthesis and Structure of [MeSi(2-C₅H₄N)₃LiX] (X = 0.2Br, 0.8Cl), F. García, A. D. Hopkins, S. M. Humphrey, M. McPartlin, M. C. Rogers, D. S. Wright, Dalton Trans. 2004, 361.
• 2,2´-Disulfanyldibenzoic Acid, S. M. Humphrey, P. T. Wood, Acta Cryst. 2003, E59, o1364.