{"id":3098,"date":"2023-05-13T05:43:03","date_gmt":"2023-05-13T05:43:03","guid":{"rendered":"https:\/\/humphrey.cm.utexas.edu\/wordpress\/?page_id=3098"},"modified":"2025-12-28T03:21:48","modified_gmt":"2025-12-28T03:21:48","slug":"publications-new","status":"publish","type":"page","link":"http:\/\/humphrey.cm.utexas.edu\/wordpress\/?page_id=3098","title":{"rendered":"Publications"},"content":{"rendered":"\n
\n

116. Phosphine and Arsine MOFs with Stabilized Diosmium(I) Carbonyl Sawhorse Pillars, S. K. Emslie, B. Patterson, A. K. Archambeau, A. H. Schumacher, R. E. Sikma, C. J. O’Dea, S. Vasylevskyi, Z. A. Page, C. B. Powell, G. Henkelman, G. L. Powell, S. M. Humphrey, Inorganic Chemistry, 2025, 23354\u201323359. DOI:10.1021\/acs.inorgchem.5c03820<\/a><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

115. Ternary Alloy Cu\u2013Ru\u2013Ir Nanocages for Acidic Oxygen Evolution Reaction, N. D’Annunzio, T. Gurusamy, H. Lee, H. Guo, W. Clark, W. A. Kristo, H. Ren, S. M. Humphrey, ACS Nano, 2025, 35551\u201335561. DOI:10.1021\/acsnano.5c09948<\/a><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

114. Organoarsine Metal\u2013Organic Framework as a Solid-State Ligand for Rhodium(I) Olefin Hydroformylation Catalysis, V. Piradi, W. Chai, S. K. Emslie, R. E. Sikma,
C. Zhang, S. Vasylevskyi, G. Henkelman, S. M. Humphrey, Journal of the American Chemical Society, 2025, 147, 32, 29110-29129. DOI:10.1021\/jacs.5c07706<\/a><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

113. Mechanisms of aqueous bromate reduction activity enhancement with well-defined bimetallic palladium-based catalysts, J. P. Troutman, J. Restivo, H. Ha, Z. Bajalan, C. E. Brady, J. M. B. Costa, C. Vigil-Hernandez, J. R. M. Barbosa, C. A. Orge, M. F. R. Pereira, S. M. Humphrey, G. Henkelman, C. J. Werth, O. S. G. P. Soares, Applied Catalysis A: General, 2024, Volume 676, 119654. DOI:10.1016\/j.apcata.2024.119654<\/a><\/span><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

112. Tuning the Selectivity of Nitrate Reduction via Fine Composition Control of RuPdNP Catalysts, J. P. Troutman, J. S. P. Mantha, H. Li, G. Henkelman, S. M. Humphrey, C. J. Werth, Small, 2024, 2308593. DOI:10.1002\/smll.20222308593<\/a><\/span><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

111. Pd\u2013Au\u2013Cu Ternary Alloy Nanoparticles: Highly Tunable and Economical Nitrite Reduction Catalysts, P. Kunal, C. Yan, H. Guo, H. Li, C. E. Brady, M. Duncan, X. Zhan, C. J. Werth, G. Henkelman, S. M. Humphrey, ACS Catalysis, 2023, 13, 11945-11953. DOI: 10.1021\/acscatal.3c01676<\/a><\/span><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

110. Low-valent Metals in Metal-organic Frameworks Via Post-synthetic Modification, J. L. Obeso, M. T. Huxley, J. A. de Los Reyes, S. M. Humphrey, I. A. Ibarra, R. A. Peralta, Angew. Chem. Int. Ed. 2023, e202309025. DOI: 10.1002\/anie.202309025<\/a><\/span><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

109. We Need to Talk about New Materials Characterization, T. W. Hayton, S. M. Humphrey, B. M. Cossairt, R. L. Brutchey, Inorganic Chemistry, 2023, 62(33), 13165-13167. DOI: 10.1021\/acs.inorgchem.3c02524<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

108. Selective adsorption of volatile organic compounds in metal-organic frameworks (MOFs), B. Siu, A. R. Chowdhury, Z. Yan, S. M. Humphrey, T. Hutter, Coordination Chemistry Reviews<\/em>, , 2023, 485, 215119. DOI: 10.1016\/j.ccr.2023.215119<\/a><\/span><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

107. Mn-CUK-1: A Flexible MOF for SO2<\/sub>, H2<\/sub>O, and H2<\/sub>S Capture, S. G. Dunning, N. K. Gupta, J. E. Reynolds III, M. Sagastuy-Bre\u00f1a, J. G. Flores, E. Mart\u00ednez-Ahumada, E. S\u00e1nchez-Gonz\u00e1lez, V. M. Lynch, A. Guti\u00e9rrez-Alejandre, J. Aguilar-Pliego, K. Kim, I. A. Ibarra, S. M. Humphrey, Inorganic Chemistry, 2022, 61(38), 15037-15044. DOI: 10.1021\/acs.inorgchem.2c02012<\/a><\/span><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

106. Sequential Post-Synthetic Modifications to a Phosphine Selenide Metal-Organic Framework: Removal of Se Protecting Group and Subsequent Coordination of Au(I) and Ag(I) to P(III) Sites, S. L. White, V. Lynch, S. G. Dunning, S. M. Humphrey, In Progress, 2021.<\/p>\n<\/div>

<\/figure><\/div>\n\n\n\n
\n

105. Investigating H2 Sorption in Isostructural Metal-Organic Frameworks M-CUK-1 (M = Co, Mg) Through Experimental and Theoretical Studies, S. Suepaul, K. A. Forrest, P. A. Georgiev, P. M. Forster, W. Lohstroh, V. Grzimek, S. G. Dunning, J. E. Reynolds III, S. M. Humphrey, J. Eckert, B. Space, T. Pham. DOI: 10.1021\/acsami.1c20312<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

104. Low-Valent Metal Ions as MOF Pillars: A New Route Toward Stable and Multifunctional MOFs, R. E. Sikma, N. Katyal, S. Lee, J. W. Fryer, C. G. Romero, S. K. Emslie, E. Taylor, V. M. Lynch, J.-S. Chang, G. Henkelman, S. M. Humphrey
J. Am. Chem. Soc., 2021, 143, 13710-13720. DOI: 10.1021\/jacs.1c05564<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

103. Magnetism and Luminescence of a MOF with Linear Mn3 Nodes Derived from an Emissive Terthiophene-Based Imidazole Linker, W. Wang, J. He, H. Guo, S. G. Dunning, S. M. Humphrey, R. A. Jones, Molecules<\/em>, 2021, 26<\/em>(14), 4286. – Alan H. Cowley Memorial Edition. DOI: 10.3390\/molecules26144286<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

102. Methods and Diversity in the Synthesis of Metal-Organic Frameworks, S. L. White, M. W. Heinz, S. M. Humphrey, Book Chapter in Comprehensive Coordination Chemistry III, Elsevier, 2021. DOI: 10.1016\/B978-0-08-102688-5.00086-6<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

101. Organometallic Chemistry at Various Length Scales: More Than Just Metal-Carbon Bonds Bring Chemists Together, J. Mindiola, M. Delferro, S. M. Humphrey, Organometallics<\/em>, 2020, 39<\/em>, 881-882. DOI: 10.1021\/acs.organomet.0c00198<\/strong><\/a><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

100. PdAg Alloy Nanocatalysts: Toward Economically Viable Nitrite Reduction in Drinking Water, J. P. Troutman, H. Li, A. M. Haddix, B. A. Kienzle, G. Henkelman, S. M. Humphrey, C. J. Werth, ACS Catal<\/em>, 2020, 10<\/em>, 7979\u20137989. DOI: 10.1021\/acscatal.0c01538<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n

<\/p>\n\n\n\n

\n

99. Cux<\/sub>Ir(1-x)<\/sub> Nanoalloy Catalyts Achieve Near 100% Selectivity for Aqueous Nitrite Reduction to NH3<\/sub> Selectivity, H. Li, C. Yan, H. Guo, K. Shin, S. M. Humphrey, C. J. Werth, G. Henkelman, ACS Catal., 2020, 10, 7915\u20137921. DOI: 10.1021\/acscatal.0c01604<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

98. Testing the Predictive Power of Theory for PdxIr(100\u2012x) Alloy Nanoparticles for the Oxygen Reduction Reaction<\/em>, H. Guo, J. Trindell, H. Li, D. Fernandez, S. M. Humphrey, G. Henkelman, R. Crooks, J. Mater. Chem. A<\/em>, 2020, 8421-8429. DOI: 10.1039\/C9TA13711D<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

97. Hydro\u00adthermal synthesis and crystal structure of poly[bis\u00ad(\u03bc3<\/sub>-3,4-di\u00adamino\u00adbenzoato)manganese], a layered coordination polymer, M. K. Khosa, P. T. Wood, S. M. Humphrey, W. T. A. Harrison, <\/span>Acta Cryst., 2020, <\/span>E76, 909-913.<\/span><\/em> DOI: 10.1107\/S2056989020006805<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

96. Reversible Solid-State Isomerism by Azobenzene-Loaded Large-Pore Isoreticular Mg-CUK-1, J. He, K. Aggarwal, N. Katyal, S. He, E. Chiang, S. G. Dunning, J. E. Reynolds III, A. Steiner, G. Henkelman, E. Que, S. M. Humphrey, J. Am. Chem. Soc., 2020, 142, 6467-6471. DOI: 10.1021\/jacs.9b13793<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

95. In situ formation of a triselenane NSeN-pincer MOF and single-crystal-to-single-crystal oxidation, S. He, L. L. Allemond, S. G. Dunning, J. E. Reynolds III, V. M. Lynch, S. M. Humphrey, Chem. Commun., 2020, 56, 1286-1289. DOI: 10.1039\/C9CC07851G<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

94. Hydrogen Evolution by Ni2P Catalysts Derived from Phosphine MOF, O. Mabayoje, S. G. Dunning, B. Wygant, R. Ciufo, K. Kawashima, S. M. Humphrey, C. B. Mullins, ACS Appl. Energy Mater., 2020, 3, 176-183. DOI: 10.1021\/acsaem.9b02109<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

93. Stabilizer-Free CuIr Alloy Nanoparticle Catalysts, H. Guo, H. Li, D. Fernandez, S. Willis, K. Jarvis, G. Henkelman, S. M. Humphrey, Chem. Mater., 2019, 31, 10225-10235. DOI: 10.1021\/acs.chemmater.9b04138<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

92. Rational Design of Rhodium-\u200bIridium Alloy Nanoparticles as Highly Active Catalysts for Acidic Oxygen Evolution, H. Guo, Z. Fang, H. Li, D. Fernandez, G. Henkelman, S. M. Humphrey, G. Yu, ACS Nano, 2019, 13, 13225-13234. DOI: 10.1021\/acsnano.9b06244<\/a><\/strong> <\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

91. Dipyrrolylnaphthyridine-based Schiff-base cryptands and their selective gas adsorption properties, F. Wang, R. E. Sikma, Z. Duan, C. Lei, Z. Zhang, S. M. Humphrey, J. L. Sessler
J. Porphyr. Phthalocya., 2019, 24, 424-431.<\/p>\n<\/div>

<\/figure><\/div>\n\n\n\n
\n

90. Accumulation-Driven Unified Spatiotemporal Synthesis and Structuring of Immiscible Metallic Nanoalloys, B. B. Rajeeva, P. Kunal, P. S. Kollipara, P. V. Acharya, M. Joe, M. S. Ide, K. Jarvis, Y. Liu, V. Bahadur, S. M. Humphrey, Y. Zheng
Matter, 2019, 1, 1606-1617. DOI: 10.1016\/j.matt.2019.10.017<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

89. Direct, One-Pot Syntheses of MOFs Decorated with Low-Valent Metal-Phosphine Complexes, S. G. Dunning, J. E. Reynolds III, K. M. Walsh, D. J. Kristek, V. M. Lynch, P. Kunal, S. M. Humphrey
Organometallics, 2019, 38, 3406-3411. DOI: 10.1021\/acs.organomet.9b00319<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

88. Porous Metal\u2013Organic Framework CUK-1 for Adsorption Heat Allocation toward Green Applications of Natural Refrigerant Water, J. S. Lee, J. W. Yoon, P. G. M. Mileo, K. H. Cho, J. Park, H. Kim, M. F. de Lange, F. Kapteijn, G. Maurin, S. M. Humphrey, J.-S. Chang, ACS App. Mater. Interfaces, 2019, 11, 25778-25789. DOI: 10.1021\/acsami.9b02605<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

87. Phosphonium zwitterions for lighter and chemically-robust MOFs: Highly reversible H2<\/sub>S capture and solvent-triggered release, J. E. Reynolds III, A. M. Bohnsack, D. J. Kristek, A. Guti\u00e9rrez-Alejandre, S. G. Dunning, N. W. Waggoner, R. E. Sikma, I. A. Ibarra, S. M. Humphrey, J. Mater. Chem. A, 2019, 7, 16842-16849. DOI: 10.1039\/C9TA05444H<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

86. Shape-persistent pyrrole-based covalent organic cages: Synthesis, structure and selective gas adsorption properties, F. Wan, R. E. Sikma, Z. Duan, T. Sarma, C. Lei, Z. Zhang, S. M. Humphrey, J. L. Sessler, Chem. Commun., 2019, 55, 6185-6188. DOI: 10.1039\/C9CC02490E<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

85. Humidity-induced CO2<\/sub> capture enhancement in Mg-CUK-1
M. Sagastuy-Bre\u00f1a, P. G. M. Mileo, E. S\u00e1nchez-Gonz\u00e1lez, J. E. Reynolds, III, T. Jurado-V\u00e1zquez, J. Balmaseda, E. Gonz\u00e1lez-Zamora, S. Devautour-Vinot, S. M. Humphrey, G. Maurin, I. A. Ibarra, Dalton Trans., 2018, 47, 15827-15834. DOI: doi.org\/10.1039\/C8DT03365J<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

84. Structural Characterization of Heterogeneous Rh-Au Nanoparticles from a Microwave-Assisted Synthesis, Z. Duan, J. Timoschenko, P. Kunal, S. House, H. Wan, K. Jarvis, C. Bonifacio, J. C. Yang, R. M. Crooks, A. I. Frenkel, S. M. Humphrey, G. Henkelman, Nanoscale<\/em>, 2018, 10<\/em>, 22520-22532. DOI: 10.1039\/C8NR04866E<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

83. Highly Selective Room Temperature Acetylene Sorption by an Unusual Triacetylenic Phosphine MOF, J. E. Reynolds III, K. M. Walsh, B. Li, P. Kunal, B. Chen, S. M. Humphrey, Chem. Commun., 2018, 54, 9937-9940. DOI: 10.1039\/C8CC05402A<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

82. An Organoarsine MOF with cis-Diarsine Pockets for the Installation of Uniquely Confined Metal Complexes, R. E. Sikma, P. Kunal, S. G. Dunning, J. E. Reynolds III, J.-S. Lee, J.-S. Chang, S. M. Humphrey, J. Am. Chem. Soc., 2018, 140, 9806-9809. DOI: 10.1021\/jacs.8b05644<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

81. Microwave-Assisted Synthesis of Classically Immiscible Ag\u2013Ir Alloy Nanoparticle Catalysts, H. Guo, H. Li, K. Jarvis, H. Wan, P. Kunal, S. G. Dunning, Y. Liu, G. Henkelman, S. M. Humphrey
ACS Catal., 2018, 8, 11386-11397. <\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

80. Highly reversible sorption of H2<\/sub>S and CO2<\/sub> by an environmentally-friendly Mg-based MOF, E. S\u00e1nchez-Gonz\u00e1lez, P. G. M. Mileo, M. Sagastuy-Bre\u00f1a, J. R. \u00c1lvarez, J. E. Reynolds III, A. Villarreal, A. Guti\u00e9rrez-Alejandre, J. Ram\u00edrez, J. Balmaseda, E. Gonz\u00e1lez-Zamora, G. Maurin, S. M. Humphrey, I. A. Ibarra
J. Mater. Chem. A, 2018, 6, 16900-16909. DOI: 10.1039\/C8TA05400B<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

79. Optothermophoretic Manipulation of Colloidal Particles in Nonionic Liquids, X. Peng, L. Lin, E. H. Hill, P. Kunal, S. M. Humphrey, and Y. Zheng, J. Phys. Chem. C, 2018, J Phys Chem C Nanomater Interfaces. DOI:10.1021\/acs.jpcc.8b0<\/strong>3828<\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

78. A MOF with Cooperative Phosphines that Permits Post\u2010Synthetic Installation of Open Metal Sites, S. G. Dunning, G. Nandra, A. D. Conn, W. Chai, R. E. Sikma, J.-S. Lee, P. Kunal, J. E. Reynolds III, J.-S. Chang, A. Steiner, G. Henkelman, S. M. Humphrey
Angew. Chem. Int. Ed., 2018, 57, 9295-9299. DOI: 10.1002\/anie.201802402<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

77. 1-D and 2-D Phosphine Coordination Materials based on a Palladium(II) PCP Pincer Metalloligand, J. He, A. M. Bohnsack, N. W. Waggoner, S. G. Dunning, V. M. Lynch, W. C. Kaska, S. M. Humphrey, Polyhedron, 2018, 143, 149-156. DOI: 10.1016\/j.poly.2017.09.025<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

76. A Survey of Metal-Organic Frameworks Based on Phosphorus- and Sulfur-Containing Building Blocks, J. E. Reynolds III, S. G. Dunning, C. M. McCulley, S. M. Humphrey, Book chapter in Elaboration and Applications of Metal-Organic Frameworks<\/em>, World Scientific, 2018. DOI: 10.1142\/9789813226739_0002<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

75. Oxygen Reduction Reaction on Classically Immiscible Bimetallics: A Case Study of RhAu, H. Li, L. Luo, P. Kunal, C. S. Bonifacio, Z. Duan, J. Yang, S. M. Humphrey, R. M. Crooks, G. Henkelman
J. Phys. Chem. C, 2018, 122, 2712-2716. DOI: 10.1021\/acs.jpcc.7b10974<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

74. Highly Selective Adsorption of p-Xylene over other C8<\/sub> Aromatic Hydrocarbons by Co-CUK-1: A Combined Experimental and Theoretical Assessment, J. W. Yoon, J. S. Lee, G. W. Piburn, K.-H. Cho, K. Jeon, H.-K. Lim, H. Kim, C.-H. Jun, S. M. Humphrey, R. Krishna, J. S. Chang, Dalton Trans.<\/em>, 2017, 46<\/em>, 16096-16101. DOI: 10.1039\/C7DT03304D<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

73. Synthesis and Characterization of a Binuclear Copper(II) Naphthoisoamethyrin Complex Displaying Weak Antiferromagnetic Coupling, J. T. Brewster II, G. Anguera, M. D. Moore, B. S. Dolinar, H. Zafar, G. D. Thiabaud, V. M. Lynch, S. M. Humphrey, J. L. Sessler, Inorg. Chem.<\/em>, 2017, 56<\/em>, 12665-12669. DOI: 10.1021\/acs.inorgchem.7b01669<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

72. Rapid Synthesis of RhPd Alloy Nanocatalysts
G. W. Piburn, H. Li, P. Kunal, G. Henkelman, S. M. Humphrey
ChemCatChem<\/em>, 2017, 10<\/em>, 329-333. DOI: 10.1002\/cctc.201701133<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

71. Magnetic Properties of the Distorted Kagom\u00e9 Lattice Mn3<\/sub>(1,2,4-(O2<\/sub>C)3<\/sub>C6<\/sub>H3<\/sub>)2<\/sub>, R. A. Mole, S. Greene, P. F. Henry, S. M. Humphrey, K. C. Rule, T. Unruh, G. F. Weldon, D. Yu, J. A. Stride, P. T. Wood
Inorg. Chem., 2017, 56, 7851-7860. DOI: 10.1021\/acs.inorgchem.7b00597<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

70. Continuous Flow Synthesis of Rh and RhAg Alloy Nanoparticle Catalysts Enables Scalable Production and Improved Morphological Control, P. Kunal, E. J. Roberts, C. T. Riche, K. Jarvis, N. Malmstadt, R. J. Brutchey, S. M. Humphrey
Chem. Mater., 2017, 29, 4341-4350. DOI: 10.1021\/acs.chemmater.7b00694<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

69. PdAu Alloy Nanoparticle Catalysts: Effective Candidates for Nitrite Reduction in Water, S. Seraj, P. Kunal, H. Li, G. Henkelman, S. M. Humphrey, C. J. Werth, ACS Catalysis, 2017, 7, 3268-3276. DOI: 10.1021\/acscatal.6b03647<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

68. A sensor for trace H2<\/sub>O detection in D2<\/sub>O, S. G. Dunning, A. J. Nunez, M. D. Moore, A. Steiner, V. M. Lynch, J. L. Sessler, B. J. Holliday, S. M. Humphrey, Chem<\/em>, 2017, 2<\/em>, 579-589. DOI: 10.1016\/j.chempr.2017.02.010<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

67. Synthesis and charge storage properties of templated LaMnO3<\/sub>-SiO2<\/sub> composite materials, G. W. Piburn, J. T. Mefford, N. Zinni, K. J. Stevenson, S. M. Humphrey, Dalton Trans.<\/em>, 2017, 46<\/em>, 977-984. DOI: 10.1039\/C6DT04665G<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

66. A PCP Pincer Ligand for Coordination Polymers with Versatile Chemical Reactivity: Selective Activation of CO2<\/sub> Gas over CO Gas in the Solid State, J. He, N. W. Waggoner, S. G. Dunning, A. Steiner, V. M. Lynch, S. M. Humphrey, Angew. Chem. Int. Ed. 2016, 55, 12351-12355. DOI: 10.1002\/anie.201604730<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

65. Microwave-\u200bAssisted Synthesis of Pdx<\/sub>Au100-\u200bx<\/sub> Alloy Nanoparticles: A Combined Experimental and Theoretical Assessment of Synthetic and Compositional Effects upon Catalytic Reactivity, P. Kunal, H. Li, B. L. Dewing, L. Zhang, K. Jarvis, G. Henkelman, S. M. Humphrey, ACS Catalysis.<\/em> 2016, 6<\/em>, 4882-4893. DOI: 10.1021\/acscatal.6b01014<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

64. Ship in a breakable bottle: fluoride-induced release of an organic molecule from a Pr(III)-linked molecular cage, J. Lee, N. W. Waggonner, L. Polanco, G. R. You, V. M. Lynch, S. K. Kim, S. M. Humphrey, J. L. Sessler, Chem. Commun. 2016, 52, 8514-8517. DOI: 10.1039\/C6CC03471C<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

63. An unusual coordination polymer containing Cu+<\/sup> ions and featuring possible Cu\u22efCu \u2018cuprophilic\u2019 interactions: poly[di-\u03bc-chlorido-(\u03bc4<\/sub>-3,5-diaminobenzoato-\u03ba4<\/sup>O:O\u2019:N:N\u2019)tricopper(I)(3 Cu-Cu)] , M. K. Khosa, P. T. Wood, S. M. Humphrey, W. T. A. Harrison, Acta Cryst.<\/em> 2016, C72<\/em>, 63-67. DOI: 10.1107\/S205322961502330X<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

62. Inelastic Neutron Scattering and Theoretical Studies of H2 Sorption in a Dy(III)-Based Phosphine Coordination Material, K. A. Forrest, T. Pham, P. A. Georgiev, J. P. Embs, N. W. Waggoner, A. Hogan, S. M. Humphrey, J. Eckert, B. Space, Chem. Mater. 2015, 27, 7619\u20137626. DOI: 10.1021\/acs.chemmater.5b02747<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

61. Separation of p-divinylbenzene by selective room-temperature adsorption inside Mg-CUK-1 prepared by aqueous microwave synthesis, B. Saccoccia, A. M. Bohnsack, N. W. Waggonner, K-H. Cho, J-S. Lee, D-Y. Hong, J-S. Chang, S. M. Humphrey, Angew. Chem. Int. Ed. 2015, 54, 5394-5398. DOI: 10.1002\/anie.201411862<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

60. Metal-Organic Frameworks as Chemical Sensors, N. W. Waggoner, A. M. Bohnsack, S. M. Humphrey, book chapter in Functional Supramolecular Materials, Royal Society of Chemistry, 2015. RSC Smart Materials, 2015, 15, 192-245.<\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

59. Magnetism of linear [Ln3<\/sub>]9+<\/sup> oxo-bridged clusters (Ln = Pr, Nd) supported inside a [R3<\/sub>PR\u2019]+<\/sup> phosphonium coordination material, N. W. Waggoner, B. Saccoccia, I. A. Ibarra, V. M. Lynch, P. T. Wood, S. M. Humphrey, Inorg. Chem. 2014, 53, 12674-12676. DOI: 10.1021\/ic5023642<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

58. Microwave synthesis of classically immiscible rhodium-silver and rhodium-gold alloy nanoparticles: Highly active hydrogenation catalysts, S. Garcia, L. Zhang, G. W. Piburn, G. Henkelman, S. M. Humphrey, ACS Nano<\/em> 2014, 8<\/em> 11512-11521. DOI: 10.1021\/nn504746u<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

57. Microwave-assisted Synthesis of Metallic Nanoparticles, S. Garcia, G. W. Piburn, S. M. Humphrey, book chapter in Microwave Engineering of Materials and Nanomaterials, Pan Stanford Publishing, 2014.<\/p>\n<\/div>

<\/figure><\/div>\n\n\n\n
\n

56. Effect of microwave heating on the synthesis of rhodium nanoparticles in ionic liquids, S. Garcia, J. J. Buckley, R. L. Brutchey, S. M. Humphrey, Inorg. Chim. Acta 2014, 422, 65-69.<\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

55. Li- and Na-reduction products of meso-Co3<\/sub>O4<\/sub> form high-rate, stably cycling battery anode materials, K. C. Klavetter, S. Garcia, N. Dahal, J. L. Snider, J. P. de Souza, T. H. Cell, M. A. Cassara, A. Heller, S. M. Humphrey, C. B. Mullins, J. Mater. Chem. A 2014, 2, 14209. DOI: 10.1039\/C4TA02684E<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

54. Bis(imino)acenaphthene (BIAN)-supported palladium(II) carbene complexes as effective C-C coupling catalysts and solvent effects in organic and aqueous media, K. A. Crawford, A. H. Cowley, S. M. Humphrey, Catal. Sci. Technol. 2014, 4, 1456. DOI: 10.1039\/C4CY00192C<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

53. Tuning the Host-Guest Interactions in a Phosphine Coordination Polymer Through Different Types of Post-Synthetic Modification, A. J. Nu\u00f1ez, Maxwell S. Chang, I. A. Ibarra, S. M. Humphrey, Inorg. Chem.<\/em> 2014, 53<\/em>, 282. DOI: 10.1021\/ic4022239<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

52. Rational Design of Porous Coordination Polymers Based on Bis(phosphine)MCl2<\/sub> Compelxes That Exhibit High-Temperature H2<\/sub> Sorption and Chemical Reactivity, A. M. Bohnsack, I. A. Ibarra, V. I. Bakhmutov, V. M. Lynch, S. M. Humphrey, J. Am. Chem. Soc. 2013, 135, 16038-16041. DOI: 10.1021\/ja408508m<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

51. Rhenium(I) Phenanthrolines Bearing Electron Withdrawing CF3<\/sub> Substituents: Synthesis, Characterization and Biological Evaluation, C. Redshaw, S. Watkins, S. M. Humphrey, P. C. B. Page, S. Ashby, Y. Chao, C. J. Herbert, A. M\u00fcller RSC Advances 2012, 3, 23963-23966. DOI: 10.1039\/C3RA43207F<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

50. Molecular Sensing and Discrimination by a Luminescent Terbium-Phosphine Oxide Coordination Material, I. A. Ibarra, T. W. Hesterberg, J. Chang, J. W. Yoon, B. J. Holliday, S. M. Humphrey, Chem. Commun.<\/em> 2013, 49<\/em>, 7156-7158. DOI: 10.1039\/C3CC44575E<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

49. Microwave Synthesis of Au-Rh Core-Shell Nanparticles and Implications of the Shell Thickness in Hydrogenation Catalysis, S. Garc\u00eda, N. Dahal, J. Zhou, H. Celio, A. Dolocan, S. M. Humphrey, Chem Commun.<\/em> 2013, 49<\/em>, 4241. DOI: 10.1039\/C3CC40387D<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

48. New Structural Motifs in Lithium and Zinc Calix[4]arene Chemistry, C. Redshaw, O. Rowe, D. L. Hughes, A. Fuller, I. A. Ibarra, and S. M. Humphrey, Dalton Trans<\/em>. 2013, 42<\/em>, 1983. DOI: 10.1039\/C2DT32986G<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

47. Beneficial Effects of Microwave-Assisted heating versus Conventional Heating in Noble Metal Nanoparticle Synthesis, N. Dahal, S. Garc\u00eda, J. Zhou, S. M. Humphrey, ACS Nano.<\/em> 2012. DOI: 10.1021\/nn3038918<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

46. Organic Vapor Sorption in a High Surface Area Dysprosium(III)-Phosphine Oxide Coordination Material, I. A. Ibarra, J. W. Yoon, J.-S. Chang, S.-K. Lee, V. M. Lynch, S. M. Humphrey, Inorg. Chem.<\/em> 2012. DOI: 10.1021\/ic301415p<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

45. Gas Sorption and Luminescence properties of a Terbium(III)-Phosphine Oxide Coordination Material with Two-Dimensional Pore Topology, Ibarra, I. A., Hesterberg, T. W., Holliday, B. D., Lynch, V. M., Humphrey, S. M., Dalton Trans.<\/em> 2012, 41<\/em>, 3920. DOI: 10.1039\/C2DT30138E<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

44. High Surface Area Mesoporous Co3<\/sub>O4<\/sub> from a Direct Soft-Template Route, N. Dahal, I. A. Ibarra, S. M. Humphrey, J. Mater. Chem.<\/em> 2012, 22<\/em>, 12675. DOI: 10.1039\/C2JM30460K<\/a><\/strong><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

43. CO2<\/sub> adsorption properties of a Ca(II)-based organophosphonium coordination material, I. A. Ibarra, K. E. Tan, V. M. Lynch, S. M. Humphrey, Dalton Trans.<\/em> 2012, 41<\/em>, 3920. DOI: 10.1039\/C2DT12011A<\/strong><\/a><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

42. A Coordination Polymer of (Ph3<\/sub>P)AuCl Prepared by Post-Synthetic Modification and its Application in 1-Hexene\/n-Hexane Separation, A. J. Nu\u00f1ez, L. N. Shear, N. Dahal, I. A. Ibarra, J. W. Yoon, J.-S. Chang, S. M. Humphrey, Chem. Commun.<\/em> 2011, 47<\/em>, 11855. DOI: 10.1039\/C1CC14682C <\/a><\/strong><\/p>\n\n\n\n

<\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n
\n

41. High capacity CO2<\/sub> adsorption in a Mg(II)-based phosphine oxide coordination material, A. M. Bohnsack, I. A. Ibarra, P. W. Hatfield, Y. K. Hwang, J. W. Yoon, J.-S. Chang, S. M. Humphrey, <\/span>Chem. Commun.<\/em> 2011, 47<\/em>, 4899. DOI: 10.1039\/C1CC14682C<\/strong><\/a><\/p>\n<\/div>

\"\"<\/figure><\/div>\n\n\n\n

Previous Publications<\/strong><\/h2>\n\n\n\n
\n
\n

40. Sonagashira coupling catalyzed by gold nanoparticles: does homogeneous or heterogeneous catalysis dominate?, G. Kyriahou, S. K. Beaumont, S. M. Humphrey, C. Antonetti, R. M. Lambert, ChemCatChem<\/em>, 2010, 2<\/em>, 1444. DOI: 10.1002\/cctc.201000154<\/a><\/strong><\/p>\n\n\n\n

39. Mixed Alkali Metal\/Transition Metal Coordination Polymers with the Mellitic Acid Hexaanion: 2-Dimensional Hexagonal Magnetic Nets, S. M. Humphrey, R. A. Mole, R. I. Thompson, P. T. Wood, Inorg. Chem. 2010, 49, 3441. DOI: 10.1021\/ic902527e<\/a><\/strong><\/p>\n\n\n\n

38. Pyridine-2,4-Dicarboxylate: A Versatile Building Block for the Preparation of Functional Coordination Polymers, S. M. Humphrey, G. F. Weldon, P. T. Wood, J. Nanosci. Nanotech. <\/em>2010, 10<\/em>, 34. DOI: 10.1166\/jnn.2010.1505<\/a><\/strong><\/p>\n\n\n\n

37. Evidence for Heterogeneous Sonogashira Coupling of Phenylacetylene and Iodobenzene Catalyzed by Well Defined Rhodium Nanoparticles, V. K. Kanuru, S. M. Humphrey, J. M. W. Kyffin, D. A. Jefferson, J. Burton, R. M. Lambert, Dalton Trans.<\/em> 2009, 7602. DOI: 10.1039\/B912833F<\/a><\/strong><\/p>\n\n\n\n

36. Metal-Organophosphine and Metal-Organophosphonium Frameworks with Layered Honeycomb-like Structures, S. M. Humphrey, P. K. Allan, S. E. Oungoulian, M. S. Ironside, E. R. Wise, Dalton Trans.<\/em> 2009, <\/em>2298. DOI: 10.1039\/B820038F<\/a><\/strong><\/p>\n\n\n\n

35. Hysteretic Sorption of Light Gases by a Porous Metal-Organic Framework Containing Tris(\u00adp\u00ad-Carboxylated) Triphenylphosphine Oxide, S. M. Humphrey, S. E. Oungoulian, Y. K. Hwang, E. R. Wise, J. W. Yoong, J.-S. Chang, Chem. Commun. <\/em>2008, <\/em>2891. DOI: 10.1039\/B802809E<\/a><\/strong><\/p>\n\n\n\n

34. A Tin(II)-Containing Ansa-Tris(allyl) ligand and its Potassium Complex, R. A. Layfield, F. Garc\u00eda, J. Hannauer, S. M. Humphrey, Chem. Commun. <\/em>2007, 5081. DOI: 10.1039\/B712285C<\/a><\/strong><\/p>\n\n\n\n

33. Bimetallic Metal-Organic Frameworks Containing the [M(2,x-pdc)2<\/sub>]2- <\/sup>(M = Cu, Pd, Pt; x = 4,5) Building Block: Synthesis, Structure and Magnetic Properties, S. M. Humphrey, T. J. P. Angliss, M. Aransay, D. Cave, L. A. Gerrard, G. F. Weldon, P. T. Wood, Zeit. Anorg. Allg. Chem. <\/em>2007, 633<\/em>, 2342. DOI: 10.1002\/zaac.200700235<\/a><\/strong><\/p>\n\n\n\n

32. Gas-Sorption Selectivity on a Porous Coordination Solid of Co(II), CUK-1, J. W. Yoon, S. H. Jhung, Y. K. Hwang, S. M. Humphrey, P. T. Wood, J.-S. Chang , Adv. Mater.<\/em> 2007, 19,<\/em> 1830. DOI: 10.1002\/adma.200601983<\/a><\/strong><\/p>\n\n\n\n

31. The Synthesis, Structure and Reactivity of B(C6<\/sub>F\u00ad5<\/sub>)3<\/sub>-Stabilised Amide (M-NH2<\/sub>) Complexes of the Group 4 Metals, A. J. Mountford, W. Clegg, S. J. Coles, R. W. Harrington, P. N. Horton, S. M. Humphrey, M. B. Hursthouse, J. A. Wright, S. J. Lancaster, Chem. Eur. J.<\/em> 2007, 13<\/em>, 4535. DOI: 10.1002\/chem.200601751<\/a><\/strong><\/p>\n\n\n\n

30. Charge-Transfer Interaction of Poly(vinylpyrrolidone) with Platinum and Rhodium Nanoparticles, Y. Borodko, S. M. Humphrey, T. D. Tilley, H. Frei, G. A. Somorjai, J. Phys. Chem. C. <\/em>2007, 111<\/em>, 6288. DOI: 10.1021\/jp068742n<\/a><\/strong><\/p>\n\n\n\n

29. Rhodium Nanoparticles from Cluster Seeds: Control of Size and Shape by Precursor Addition Rate, S. M. Humphrey, M. E. Grass, S. E. Habas, K. Niesz, G. A. Somorjai, T. D. Tilley, Nano Lett.<\/em> 2007, 7<\/em>, 785. DOI: 10.1021\/nl070035y<\/a><\/strong><\/p>\n\n\n\n

28. Porous Cobalt(II)-Organic Frameworks with Corrugated Walls: Robust Gas-Sorption Materials, S. M. Humphrey, J.-S. Chang, S. H. Jhung, J. W. Yoon, P. T. Wood, Angew. Chem., Int. Ed.<\/em> 2007, 46<\/em>, 272. DOI: 10.1002\/anie.200601627<\/a><\/strong><\/p>\n\n\n\n

27. The Cationic Cluster Grignard [{MgCl(thf)2<\/sub>}3<\/sub>(\u03b73<\/sub>-C3<\/sub>H5<\/sub>)2<\/sub>]+<\/sup>, R. A. Layfield, T. H. Bullock, F. Garc\u00eda, S. M. Humphrey, P. Sch\u00fcler, Chem. Commun. <\/em>2006, 2039. DOI: 10.1039\/B602059C<\/a><\/strong><\/p>\n\n\n\n

26. A New Co(II) Coordination Solid with Mixed Oxygen, Carboxylate, Pyridine and Thiolate Donors Exhibiting Canted Antiferromagnetism with Tc<\/sub> \u2248 68 K, S. M. Humphrey, A. Alberola, C. J. G\u00f3mez Garc\u00eda, P. T. Wood, Chem. Commun. <\/em>2006, 1607. DOI: 10.1039\/B600347H<\/a><\/strong><\/p>\n\n\n\n

25. Complexes of Tungsten (IV,VI) Derived from Linked Aryloxide Ligands, C. Redshaw, S. M. Humphrey, Polyhedron<\/em> 2006, 25<\/em>, 1946. DOI: 10.1016\/j.poly.2005.12.008 <\/a><\/strong><\/p>\n\n\n\n

24. Spin Transitions in a Dithiazolyl Radical: Preparation, Crystal Structures and Magnetic Properties of 3-Cyanobenzo-1,2,3-dithiazolyl, C7<\/sub>H3<\/sub>S2<\/sub>N2<\/sub>\u2022, A. Alberola, R. J. Collis, S. M. Humphrey, R. J. Less, J. M. Rawson, Inorg. Chem. <\/em>2006, 45<\/em>, 1903. DOI: 10.1021\/ic051935p<\/a><\/strong><\/p>\n\n\n\n

23. Ligand Transfer Reactions of Mixed-Metal Lanthanide\/Magnesium Allyl Complexes with b-Diketimines: Synthesis, Structures, and Ring-Opening polymerization Catalysis, L. F. S\u00e1nchez-Barba, D. L. Hughes, S. M. Humphrey, M. Bochmann, Organometallics<\/em>, 2006, 25<\/em>, 1012. DOI: 10.1021\/om050892h<\/a><\/strong><\/p>\n\n\n\n

22. Titanium, Zinc and Alkaline-Earth Metal Complexes Supported by Bulky O,N,N,O-Multidentate Ligands: Synthesis, Characterisation and Activity in Cyclic Ester Polymerisation, Y. Sarazin, R. H. Howard, D. L. Hughes, S. M. Humphrey, M. Bochmann, Dalton Trans.<\/em> 2006, <\/em>340. DOI: 10.1021\/om050892h<\/a><\/strong><\/p>\n\n\n\n

21. EPR Studies on the Thiophenodithiazolyl radical, C4<\/sub>H2<\/sub>S3<\/sub>N\u2022, A. Alberola, R. D. Farley, S. M. Humphrey, G. D. McManus, D. M. Murphy, J. M. Rawson, Dalton Trans<\/em>. 2005, 3838. DOI: 10.1039\/B508912C<\/a><\/strong><\/p>\n\n\n\n

20. Synthesis and Structure of [trans-{1,2-Bis(\u03b72<\/sup>-O,N,N-phenylcarbamoyl)cyclopentadienyl bis(thf)} magnesium]\u00b74thf, R. A. Layfield, S. M. Humphrey, Organometallics <\/em>2005, 24<\/em>, 6063. DOI: 10.1021\/om050680k<\/a><\/strong><\/p>\n\n\n\n

19. Synthesis and Structures of New Mixed-Metal Lanthanide\/Magnesium Allyl Complexes, L. F. S\u00e1nchez-Barba, D. L. Hughes, S. M. Humphrey, M. Bochmann, Organometallics <\/em>2005, 24<\/em>, 5329. DOI: 10.1021\/om0505155<\/a><\/strong><\/p>\n\n\n\n

18. Isolated Magnetic Clusters of Co(II) and Ni(II) within 3-Dimensional Organic Frameworks of 6-Mercaptonicotinic Acid: Unique Structural Topologies Based on Selectivity for Hard and Soft Coordination Environments, S. M. Humphrey, R. A. Mole, M. McPartlin, E. J. L. McInnes, P. T. Wood, Inorg. Chem. <\/em>2005, 44<\/em>, 5981. DOI: 10.1021\/ic050768q<\/a><\/strong><\/p>\n\n\n\n

17. New Bis(allyl)(diketiminato) and Tris(allyl) Lanthanide Complexes and Their Reactivity in the Polymerization of Polar Monomers, L. F. S\u00e1nchez-Barba, D. L. Hughes, S. M. Humphrey, M. Bochmann, Organometallics <\/em>2005, 24<\/em>, 3792. DOI: 10.1021\/om050309x<\/a><\/strong><\/p>\n\n\n\n

16. Quadruple Deprotonation of 2-Aminophenylphosphane with a p-Block-Metal\/Alkali-Metal Base, F. Garc\u00eda, S. M. Humphrey, R. A. Kowenicki, E. J. L. McInnes, C. M. Pask, M. McPartlin, J. M. Rawson, M. L. Stead, A. D. Woods, D. S. Wright, Angew. Chem., Int. Ed.<\/em> 2005, 44<\/em>, 3456. DOI: 10.1002\/anie.200500340<\/a><\/strong><\/p>\n\n\n\n

15. New Titanium and Zirconium Complexes with M-NH2<\/sub> Bonds Formed by Facile Deprotonation with H3<\/sub>N\u00b7B(C6<\/sub>F5<\/sub>)3<\/sub>, A. J. Mountford, W. Clegg, R. W. Harrington, S. M. Humphrey. S. J. Lancaster, Chem. Commun.<\/em> 2005, 2044. DOI: 10.1039\/B500407A<\/a><\/strong><\/p>\n\n\n\n

14. Variable Solid State Aggregations in a Series of (Isocyanide)Gold(I) Halides with the Novel Trimethylamine-Isocyanoborane Adduct, S. M. Humphrey, H-G. Mack, C. Redshaw, M. R. J. Elsegood, K. J. H. Young, H. A. Mayer, W. C. Kaska, Dalton Trans.<\/em> 2005, 439. DOI: 10.1039\/B416392C<\/a><\/strong><\/p>\n\n\n\n

13. Synthesis, Ion Aggregation, Alkyl Bonding Modes, and Dynamics of 14-Electron Matallocenium Ion Pairs [(SBI)MCH2<\/sub>SiMe3<\/sub>+<\/sup>\u00b7\u00b7\u00b7X–<\/sup>] (M = Zr, Hf): Inner-Sphere (X = MeB(C6<\/sub>F5<\/sub>)3<\/sub>) Structures versus Outer-Sphere (X = B(C6<\/sub>F5<\/sub>)4<\/sub>) Structures and the Implications for \u201cContinuous\u201d or \u201cintermittent\u201d Alkene Polymerization Mechanisms, F. Song, S. J. Lancaster, R. D. Cannon, M. Schormann, S. M. Humphrey, C. Zuccaccia, A. Macchioni, M. Bochmann, Organometallics<\/em> 2005, 24<\/em>, 1315. DOI: 10.1021\/om049248d<\/a><\/strong><\/p>\n\n\n\n

12. Highly Selective Epoxidation of Styrene using a Transition Metal-Aluminium(III) Complex Containing the [MeAl(2-py)3<\/sub>]–<\/sup> Anion (2-py = 2-pyridyl), C. Soria Alvarez, F. Garc\u00eda, S. M. Humphrey, A. D. Hopkins, R. A. Kowenicki, M. McPartlin, R. A. Layfield, R. Raja, M. C. Rogers, A. D. Woods, D. S. Wright, Chem. Commun.<\/em> 2005, 198. DOI: 10.1039\/B413488E<\/a><\/strong><\/p>\n\n\n\n

11. Acid\/Amide Bonding for Anthranilic Acid Derivatives: Crystal Structures [W(X)Cl3(HO2<\/sub>CC6<\/sub>H4<\/sub>NH-2)] (X = O, NPh), S. M. Humphrey, C. Redshaw, K. E. Holmes, M. R. J. Elsegood, Inorg. Chim. Acta <\/em>2005, 358<\/em>, 222. DOI: 10.1039\/B413488E<\/a><\/strong><\/p>\n\n\n\n

10. Synthesis and Structure of [{Sn2<\/sub>(\u03b7-PMes)3<\/sub>}K2<\/sub>\u00b73THF}\u221e<\/sub>, Exhibiting Multifunctional Coordination of [Sn2<\/sub>(m-PMes)3<\/sub>]2-<\/sup> Anions to K+<\/sup>, F. Garc\u00eda, A. D. Hopkins, S. M. Humphrey, M. McPartlin, C. M. Pask, A. D. Woods, D. S. Wright, Organometallics<\/em> 2004, 23<\/em>, 4821. DOI: 10.1021\/om0495372<\/a><\/strong><\/p>\n\n\n\n

9. Multiple Areas of Magnetic Bistability in the Topological Ferrimagnet [Co3<\/sub>(NC5<\/sub>H3<\/sub>(CO2<\/sub>)2<\/sub>-2,5)2<\/sub>(\u03bc3<\/sub>-OH)2<\/sub>(OH2<\/sub>)2<\/sub>], S. M. Humphrey, P. T. Wood, J. Am. Chem. Soc.<\/em> 2004, 126<\/em>, 13236. DOI: 10.1021\/ja046351l<\/a><\/strong><\/p>\n\n\n\n

8. Synthesis and Structure of [{Sn2<\/sub>(\u03b7-PMes)3<\/sub>}K2<\/sub>\u00b73THF}\u221e<\/sub>, Exhibiting Multifunctional Coordination of [Sn2<\/sub>(m-PMes)3<\/sub>]2-<\/sup> Anions to K+<\/sup>, F. Garc\u00eda, A. D. Hopkins, S. M. Humphrey, M. McPartlin, C. M. Pask, A. D. Woods, D. S. Wright, Organometallics<\/em> 2004, 23<\/em>, 4821. DOI: 10.1021\/om0495372<\/a><\/strong><\/p>\n\n\n\n

7. [{H3<\/sub>C)3<\/sub>NB(H)2<\/sub>NC}2<\/sub>Au][AuI2<\/sub>]: A Linear Chain Polymer of Gold(I) Iodide with an Unusual Isocyanoborane Ligand Showing Aurophilic Behaviour, W. C. Kaska, H. A. Mayer, M. R. J. Elsegood, P. N. Horton, M. B. Hursthouse, C. Redshaw, S. M. Humphrey, Acta Cryst.<\/em> 2004, E60<\/em>, m563. DOI: 10.1107\/S1600536804008098<\/a><\/strong><\/p>\n\n\n\n

6. A Manganese(II) Allyl Complex: Synthesis, Structure and Magnetic Properties of [Li(thf)4<\/sub>][Mn{\u03b73<\/sup>-(Me3<\/sub>Si)2<\/sub>C3<\/sub>H3<\/sub>}{\u03b71<\/sup>-(Me3<\/sub>Si)2<\/sub>C3<\/sub>H3<\/sub>}2<\/sub>], R. A. Layfield, S. M. Humphrey, Angew. Chem., Int. Ed.<\/em> 2004, 43<\/em>, 3067. DOI: 10.1002\/ange.200454008<\/a><\/strong><\/p>\n\n\n\n

5. Hydrothermal Synthesis and Magnetic Properties of Novel Mn(II) and Zn(II) Materials with Thiolato-Carboxylate Donor Ligand Frameworks, S. M. Humphrey, R. A. Mole, J. M. Rawson, P. T. Wood, Dalton Trans.<\/em> 2004, 1670. DOI: 10.1039\/B401887G<\/a><\/strong><\/p>\n\n\n\n

4. Selective Formation of the [PhP(H)-PPh]–<\/sup> Anion in the Reaction of PhPHLi with MeAlCl2<\/sub>: Synthesis and Structure of the Unusual Tetramer [{PhP(H)-PPh}Li\u00b7thf]4<\/sub>, F. Garc\u00eda, S. M. Humphrey, R. A. Kowenicki, M. McPartlin, D. S. Wright, Dalton Trans. <\/em>2004, 977. DOI: 10.1039\/B402295E<\/a><\/strong><\/p>\n\n\n\n

3. Steric Control in the Oligomerization of Phosphazene Dimers; Towards New Phosphorus-Nitrogen Macrocycles, E. L. Doyle, F. Garc\u00eda, S. M. Humphrey, R. A. Kowenicki, L. Riera, A. D. Woods, D. S. Wright, Dalton Trans. <\/em>2004, 807. DOI: 10.1039\/B314790H<\/a><\/strong><\/p>\n\n\n\n

2. The First Example of a Si-Bridged Tris(pyridyl) Ligand; Synthesis and Structure of [MeSi(2-C5<\/sub>H4<\/sub>N)3<\/sub>LiX] (X = 0.2Br, 0.8Cl), F. Garc\u00eda, A. D. Hopkins, S. M. Humphrey, M. McPartlin, M. C. Rogers, D. S. Wright, Dalton Trans.<\/em> 2004, 361. DOI: 10.1039\/B315503J<\/a><\/strong><\/p>\n\n\n\n

1. 2,2\u00b4-Disulfanyldibenzoic Acid, S. M. Humphrey, P. T. Wood, Acta Cryst. <\/em>2003, E59<\/em>, o1364. DOI: 10.1107\/S1600536803017306<\/a><\/strong><\/p>\n<\/div>\n<\/div>\n\n\n\n

<\/p>\n","protected":false},"excerpt":{"rendered":"

116. Phosphine and Arsine MOFs with Stabilized Diosmium(I) Carbonyl Sawhorse Pillars, S. K. Emslie, B. Patterson, A. K. Archambeau, A. H. Schumacher, R. E. Sikma, C. J. O’Dea, S. Vasylevskyi, Z. A. Page, C. B. Powell, G. Henkelman, G. L. Powell, S. M. Humphrey, Inorganic Chemistry, 2025, 23354\u201323359. DOI:10.1021\/acs.inorgchem.5c03820 115. Ternary Alloy Cu\u2013Ru\u2013Ir Nanocages for […]<\/p>\n","protected":false},"author":12,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"hide_page_title":"","footnotes":""},"class_list":["post-3098","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"http:\/\/humphrey.cm.utexas.edu\/wordpress\/index.php?rest_route=\/wp\/v2\/pages\/3098","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/humphrey.cm.utexas.edu\/wordpress\/index.php?rest_route=\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/humphrey.cm.utexas.edu\/wordpress\/index.php?rest_route=\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/humphrey.cm.utexas.edu\/wordpress\/index.php?rest_route=\/wp\/v2\/users\/12"}],"replies":[{"embeddable":true,"href":"http:\/\/humphrey.cm.utexas.edu\/wordpress\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=3098"}],"version-history":[{"count":78,"href":"http:\/\/humphrey.cm.utexas.edu\/wordpress\/index.php?rest_route=\/wp\/v2\/pages\/3098\/revisions"}],"predecessor-version":[{"id":3834,"href":"http:\/\/humphrey.cm.utexas.edu\/wordpress\/index.php?rest_route=\/wp\/v2\/pages\/3098\/revisions\/3834"}],"wp:attachment":[{"href":"http:\/\/humphrey.cm.utexas.edu\/wordpress\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=3098"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}